不同碳饱和水平下典型农田土壤有机质的红外光谱特征

doi:10.3864/j.issn.0578-1752.2018.16.008

Abstract

Abstract: 【Objective】 The objective of this study is to explore the infrared spectra characteristics of soil organic carbon (SOC) with different SOC saturation levels under different long-term fertilization. 【Method】 Based on two long-term experiments at Jinxian (Red soil with double rice cropping) and Yuanyang (Fluvo-aquic soil with winter wheat-summer maize cropping) sites, the typical fertilizer treatments were selected. The saturation deficit (SD) under different treatments was calculated and analyzed. The different functional groups were measured by Fourier transform infrared spectroscopy (FTIR), and then the characteristics among different treatments were analyzed. 【Result】 It was linear relationship between SOC annual change rate and C input at Yuanyang, while the asymptotic line at Jinxian. The SD value at Jinxian (0.118-0.413) was obviously smaller than that at Yuanyang (0.462-0.616). The similar functional groups such as aromatic (1 636 cm^-1, 695 cm^-1), aliphatic (3 000-2 850 cm^-1,1 455 cm^-1), carbohydrate /polysaccharides (1 080 cm^-1,1 033cm^-1/1 034 cm^-1) and organosilicone (1 100-1 008 cm^-1, 526 cm^-1, 795 cm^-1, 778 cm^-1, 470 cm^-1) were both at Jinxian and Yuanyang sites. The absorption intensity of aromatic, aliphatic and organosilicone series was clearly stronger at Jinxian than that at Yuanyang, while the absorption intensity of carboxyl, alkane and carbohydrate was stronger at Yuanyang than that at Jinxian. The SOC content was negatively correlated with light transmittance. Compared with Yuanyang, the carbon input, clay content and iron-aluminum oxides were higher in Jinxian. Furthermore, the water regime with double rice at Jinxian was more benefit for SOC accumulation. 【Conclusion】 The results of the relationship between SOC change rate and C input and the SD value indicated that the higher saturation level appeared at Jinxian site. There were more recalcitrant components like aromatics, aliphatic and organosilicone at Jinxian, while the labile component like carboxyl, alkanes and carbohydrate appeared at Yuanyang. The infrared transmittance could quantify the function group to some extent.

Key words: carbon saturation, soil organic matter, spectral characteristics, functional groups, fluvo-aquic soil, red soil

JIANG GuiYing, ZHANG YuJun, WEI Xi, ZHANG DongXu, LIU ShiLiang, LIU KaiLou, HUANG ShaoMin, SHEN FengMin. The Soil Infrared Spectral Characteristics of Soil Organic Matter under Different Carbon Saturation Levels[J].Scientia Agricultura Sinica, 2018, 51(16): 3117-3129.

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