Scientia Agricultura Sinica ›› 2012, Vol. 45 ›› Issue (4): 743-751.doi: 10.3864/j.issn.0578-1752.2012.04.015

• STORAGE·FRESH-KEEPING·PROCESSING • Previous Articles     Next Articles

Effects of the Residues of Agricultural Chemicals in Grapes on Winemaking

 LI  Ji-Ming, SI  He-Yun, YU  Ying, DUAN  Hui, LIANG  Dong-Mei, JIANG  Wen-Guang, LI  Xue-Hui   

  1. 1.张裕集团有限公司技术中心,山东烟台 264001
  • Received:2011-08-10 Online:2012-02-15 Published:2011-12-23

Abstract: 【Objective】The residues of agricultural chemicals in grapes and wines from three grapevine varieties in Yantai region were monitored, with the aim to investigate the influence of agricultural chemicals on grape fermentation and wine quality.【Method】The organophosphorous and organochlorine pesticide residues in grape and wine were determined by using gas chromatography-flame photometric detection (GC-FPD) and gas chromatography-electron capture detector (GC-ECD), respectively. 【Result】The striazolone was detected in all grape samples of Cabernet Sauvignon and Chardonnay from four areas in Yantai. Its average content was 71.09 µg•kg-1. Benzene hexachloride was found in Chardonnay from plot 1 and in Cabernet Sauvignon from plot 3, with the concentrations of 2.23 µg•kg-1 and 4.86 µg•kg-1, respectively. Cyhalothrin was found in two grape cultivars from plot 2 and 3, and its concentration ranged from 2.36 µg•kg-1 to 7.51 µg•kg-1 with a mean content of 4.28 µg•kg-1. Among the four agricultural chemicals tested, miconazole nitrate had the strongest inhibitory effect, because the alcoholic fermentation ceased when the amount of this compound exceeded 0.20 g•kg-1. After wine-making, the content of residues of agricultural chemicals in wines were quantified, and benzene hexachloride presented the highest transfer rate from grape to wine (32.14%), whereas chlorothalonil, cyhalothrin and triadimefon showed the values never higher than 0.7%. 【Conclusion】 The residues of agricultural chemicals in wine grapes in Yantai region fulfilled the related requirements. The residues of agricultural chemicals had some effects on fermentation process and generate off-flavors that will negatively affect the sensory of wines. However, the content of residues were reduced evidently during winemaking, and varied significantly in the final products depending on the characteristics of agricultural chemicals.

Key words: grape, wine, agricultural chemical, sensory quality

[1]赵红刚. 果树生产中农药的污染问题及治理对策. 烟台果树, 2007(4): 4-5.

Zhao H G. The problem of pesticides residue in fruit tree production and its countermeasures. Yantai Fruits, 2007(4): 4-5. (in Chinese)

[2]李海兰, 叶慧琼, 王忠跃, 战吉宬, 黄卫东. 3种杀真菌剂对葡萄酒酿酒酵母生长和发酵性能的影响. 中外葡萄与葡萄酒, 2009(7): 5-9.

Li H L, Ye H Q, Wang Z Y, Zhan J C, Huang W D. Influence of three fungicides on growth and fermentability of wine yeast. Sino-Overseas Grapevine & Wine, 2009(7): 5-9. (in Chinese)

[3]淑  英, 王  华, 王贞强. 我国和CAC葡萄农药残留标准比较. 中外葡萄与葡萄酒, 2005(3): 45-47.

Shu Y, Wang H, Wang Z Q. Compare the standards of MRLs on grape between China and CAC. Sino-Overseas Grapevine & Wine, 2005(3): 45-47. (in Chinese)

[4]赖穗春, 王富华, 邓义才, 杜应琼, 徐爱平, 黄洁晖. 国内外农药残留分析技术研究现状与发展. 广东农业科学, 2006(1):76-77.

Lai S C, Wang F H, Deng Y C, Du Y Q, Xu A P, Huang J H. Actual state and development of domestic and foreign techniques for analysis of agricultural chemicals residue. Guangdong Agricultural Sciences, 2006(1):76-77.(in Chinese)

[5]淑  英, 王  华, 王贞强. 葡萄酒中农药残留的色谱分析法研究进展. 中国农业通报, 2005, 21(8):65-69.

Shu Y, Wang H, Wang Z Q. Advances of studies on analytical methods for pesticide residues in wine with chromatographic. Chinese Agricultural Science Bulletin, 2005, 21(8): 65-69. (in Chinese)

[6]王金芳, 栾  鸾, 王正全, 江树人, 潘灿平. 微液液提取或固相微萃取法净化、气相色谱-质谱联用检测葡萄酒中19种农药残留. 分析化学, 2007, 35(10): 1430-1434.

Wang J F, Luan Y, Wang Z Q, Jiang C R, Pan C P. Determination of 19 multi-residue pesticides in grape wine by gas chromatography-mass spectrometry with micro liquid-liquid extraction and solid phase extraction. Chinese Journal of Analytical Chemistry, 2007, 35(10): 1430-1434. (in Chinese)

[7]González-Rodríguez R M, Cancho-Grande B, Torrado-Agrasar A, Simal-Gándara J, Mazaira-Pérez J. Evolution of Tebuconazole Residues through the winemaking process of Mencia grape. Food Chemistry, 2009, 117: 529-537.

[8]Cus F, Cesnik H B, Bolta S V, Gregorcic A. Pesticide residues in grapes and during vinification process. Food Control, 2010, 21 (11): 1512-1518.

[9]Cabras P, Garau V L, Pirisi F M, Cubeddu M, Cabitza F, Spanedda L. Fate of some insecticides from vine to wine. Journal of Agricultural and Food Chemistry, 1995, 43(10): 2613-2615.

[10]Fernández M J, Oliva J, Barba A, Cámara M A. Effects of clarification and filtration processes on the removal of fungicides residues in red wine (Var Monastrell). Journal of Agricultural and Food Chemistry, 2005, 53(15): 6156-6161.

[11]González-Rodríguez R M, Noguerol-Pato R, González-Barreiro C, Cancho-Grande B, Simal-Gándara J. Application of new fungicides under good agricultural practices and their effects on the volatile profile of white wines. Food Research International, 2011, 44:397-403.

[12]李  华. 葡萄酒工艺学. 北京: 科学出版社, 2008.

Li H. Modern Enology. Beijing: Science Press, 2008. (in Chinese)

[13]中华人民共和国农业部. 绿色食品——葡萄(NY/T428—2000). 2000.

Ministry of Agriculture of the People's Republic of China. Green food-Grape (NY/T428—2000). 2000. (in Chinese)

[14]中华人民共和国国家质量监督检验检疫总局. 农产品安全质量无公害水果安全要求 (GB18406.2—2001). 2001.

General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China (AQSIQ). Safety qualification for agricultural product-Safety requirements for non- environmental pollution fruit (GB18406.2—2001). 2001. (in Chinese)

[15]中华人民共和国卫生部, 中国国家标准化管理委员会. 食品中农药最大残留限量(GB 2763—2005). 2005.

Ministry of Public Health of the People's Republic of China, Sac Standardization Administration of China. Maximum residue limits for pesticides in food (GB 2763—2005). 2005. (in Chinese)

[16]Calhelha R C, Andrade J V, Ferreira I C, Estevinho L M. Toxicity effects of fungicide residues on the wine-producing process. Food Microbiology, 2006, 23(4):393-398.

[17]Paolo C, Alberto A, Vincenzo LG, Melis M, Pirisi F M, Farris G, Sotgiu C, Minelli E V. Persistence and metabolism of folpet in grapes and wine. Journal of Agricultural and Food Chemistry, 1997, 45(2): 476-479.

[18]Polsinelli M, Vandini C. Studies on the effects of fungicides on wine yeasts. Vignevini, 2003, 30(11): 137-139.

[19]De Melo Abreu S, Caboni P, Pirisi F M, Cabras P, Alves A, Garau V L. Residues of the fungicide famoxadone in grape and its fate during wine production. Food Additives and Contaminants, 2006, 23(3): 289-294.

[20]Ruediger G, Sas A, Pollnitz A P, Pardon K H, Godden P. Removal of pesticides from red and white wine by the use of fining and filter agents. Australian Journal of Grape and Wine Research, 2004, 10(1): 8-16.

[21]Soles G J, Goldberg D M. Pesticide residues in unfermented grape juice and raw wines: A 5-year survey of more 3000 products. Journal of Wine Research, 2000, 11(3):197-207.

[22]Cabras P, Angioni A, Garau V L, Pirisi F M, Farris G A, Madau G, Emonti G. Pesticides in fermentative processes of wine. Journal of Agricultural and Food Chemistry, 1999, 47(9):3854-3857.

[23]The codex commission pesticide residues (CCPR). Codex maximum residue limits for pesticides (CAC/MRL01-2001). 2001.

[24]刘  文, 云振宇, 王乃铝, 许建军, 李  强, 蔡晓湛. 我国与国际食品法典委员会(CAC)食品中农药最大残留量标准的对比分析研究. 食品工业科技, 2009, 30(6): 380-382.

Liu W, Yun Z Y, Wang N L, Xu J J, Li Q, Cai X Z. Study in comparison and analysis on standards of pesticide maximum residue limits in food between international codex alimentarius commission and China national standards. Science and Technology of Food Industry, 2009, 30(6): 380-382. (in Chinese)

[25]The Australian Wine Research Institute. Agrochemicals registered for use in Australian viticulture. 2010. http://www.awri.com.au/industry% 5Fsupport/viticulture/agrochemicals/mrls/search.asp, 2011-01-10.
[1] ZHANG KeKun,CHEN KeQin,LI WanPing,QIAO HaoRong,ZHANG JunXia,LIU FengZhi,FANG YuLin,WANG HaiBo. Effects of Irrigation Amount on Berry Development and Aroma Components Accumulation of Shine Muscat Grape in Root-Restricted Cultivation [J]. Scientia Agricultura Sinica, 2023, 56(1): 129-143.
[2] ZHAI XiaoHu,LI LingXu,CHEN XiaoZhu,JIANG HuaiDe,HE WeiHua,YAO DaWei. Quantitative Detection Technology of Porcine-Derived Materials in Meat by Real-time PCR [J]. Scientia Agricultura Sinica, 2023, 56(1): 156-164.
[3] WANG YiDan,YANG FaLong,CHEN DiShi,XIANG Hua,REN YuPeng. One-Step Multiple TaqMan Real-time RT-PCR for Simultaneous Detection of Swine Diarrhea Viruses [J]. Scientia Agricultura Sinica, 2023, 56(1): 179-192.
[4] LÜ XinNing,WANG Yue,JIA RunPu,WANG ShengNan,YAO YuXin. Effects of Melatonin Treatment on Quality of Stored Shine Muscat Grapes Under Different Storage Temperatures [J]. Scientia Agricultura Sinica, 2022, 55(7): 1411-1422.
[5] GUO ZeXi,SUN DaYun,QU JunJie,PAN FengYing,LIU LuLu,YIN Ling. The Role of Chalcone Synthase Gene in Grape Resistance to Gray Mold and Downy Mildew [J]. Scientia Agricultura Sinica, 2022, 55(6): 1139-1148.
[6] WANG HuiLing, YAN AiLing, SUN Lei, ZHANG GuoJun, WANG XiaoYue, REN JianCheng, XU HaiYing. eQTL Analysis of Key Monoterpene Biosynthesis Genes in Table Grape [J]. Scientia Agricultura Sinica, 2022, 55(5): 977-990.
[7] YANG ShiMan, XU ChengZhi, XU BangFeng, WU YunPu, JIA YunHui, QIAO ChuanLing, CHEN HuaLan. Amino Acid of 225 in the HA Protein Affects the Pathogenicities of H1N1 Subtype Swine Influenza Viruses [J]. Scientia Agricultura Sinica, 2022, 55(4): 816-824.
[8] WANG Bo,QIN FuQiang,DENG FengYing,LUO HuiGe,CHEN XiangFei,CHENG Guo,BAI Yang,HUANG XiaoYun,HAN JiaYu,CAO XiongJun,BAI XianJin. Difference in Flavonoid Composition and Content Between Summer and Winter Grape Berries of Shine Muscat Under Two-Crop-a-Year Cultivation [J]. Scientia Agricultura Sinica, 2022, 55(22): 4473-4486.
[9] LIU Xin,ZHANG YaHong,YUAN Miao,DANG ShiZhuo,ZHOU Juan. Transcriptome Analysis During Flower Bud Differentiation of Red Globe Grape [J]. Scientia Agricultura Sinica, 2022, 55(20): 4020-4035.
[10] MA YuQuan,WANG XiaoLong,LI YuMei,WANG XiaoDi,LIU FengZhi,WANG HaiBo. Differences in Nutrient Absorption and Utilization of 87-1 Grape Variety Under Different Rootstock Facilities [J]. Scientia Agricultura Sinica, 2022, 55(19): 3822-3830.
[11] ZHANG FengXi,XIAO Qi,ZHU JiaPing,YIN LiHong,ZHAO XiaLing,YAN MingShuai,XU JinHua,WEN LiBin,NIU JiaQiang,HE KongWang. Preparation and Identification of Monoclonal Antibodies to P30 Protein and Establishment of Blocking ELISA to Detecting Antibodies Against African Swine Fever Virus [J]. Scientia Agricultura Sinica, 2022, 55(16): 3256-3266.
[12] WEI Tian,WANG ChengYu,WANG FengJie,LI ZhongPeng,ZHANG FangYu,ZHANG ShouFeng,HU RongLiang,LÜ LiLiang,WANG YongZhi. Preparation of Monoclonal Antibodies Against the p30 Protein of African Swine Fever Virus and Its Mapping of Linear Epitopes [J]. Scientia Agricultura Sinica, 2022, 55(15): 3062-3070.
[13] JI XiaoHao,LIU FengZhi,WANG BaoLiang,LIU PeiPei,WANG HaiBo. Genetic Variation of Alcohol Acyltransferase Encoding Gene in Grape [J]. Scientia Agricultura Sinica, 2022, 55(14): 2797-2811.
[14] YANG ShengDi,MENG XiangXuan,GUO DaLong,PEI MaoSong,LIU HaiNan,WEI TongLu,YU YiHe. Co-Expression Network and Transcriptional Regulation Analysis of Sulfur Dioxide-Induced Postharvest Abscission of Kyoho Grape [J]. Scientia Agricultura Sinica, 2022, 55(11): 2214-2226.
[15] HAN Xiao, YANG HangYu, CHEN WeiKai, WANG Jun, HE Fei. Effects of Different Rootstocks on Flavonoids of Vitis vinifera L. cv. Tannat Grape Fruits [J]. Scientia Agricultura Sinica, 2022, 55(10): 2013-2025.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
No Suggested Reading articles found!