Scientia Agricultura Sinica ›› 2012, Vol. 45 ›› Issue (24): 5057-5064.doi: 10.3864/j.issn.0578-1752.2012.24.011

• SOIL & FERTILIZER·WATER-SAVING IRRIGATION·AGROECOLOGY & ENVIRONMENT • Previous Articles     Next Articles

Retention and Desorption of Exogenous Chlortetracycline(CTC) on Corn-Straw Derived Biochar

 GUAN  Lian-Zhu, ZHAO  Ya-Ping, ZHANG  Guang-Cai, ZHANG  Yun, YAN  Li   

  1. College of Land and Environment, Shenyang Agricultural University, Shenyang 110866
  • Received:2012-06-14 Online:2012-12-15 Published:2012-08-08

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Abstract: 【Objective】 In order to reduce chlortetracycline (CTC) pollution from waste water and animal dung, the retention and desorption characteristics of exogenous CTC onto the corn-straw derived biochar were studied. 【Method】The OECD Guideline106 batch equilibrium method was used to study the adsorption kinetics and adsorption-desorption thermodynamic characteristics of CTC onto the corn-straw derived biochar. 【Result】 The results showed that the retention kinetics of CTC onto the tested biochar included two stages of rapid response and slow balance. Twelve hours was taken to reach the retention equilibrium. The retention behavior of CTC onto the tested biochar fitted second-order kinetics model (average R2 is 0.9999) well. The retention isotherm at different temperatures fitted Freundlich model (average R2 is 0.9174) well. The adsorption capacity (lgKf = 3.6575-3.7377) and the adsorption intensity (1 / n = 0.8647-1.0478) were both high and became higher as temperature increasing. The shape of adsorption isotherm gradually changed from L-shaped to linear as temperature increasing; the retention of CTC onto the tested biochar was a spontaneous endothermic process and the main mechanism was physical retention. The desorption rate of CTC on the tested biochar varied from 2.57% to 6.99% and decreased with the temperature increasing, which meant the retention of CTC on the corn-straw derived biochar was more firm when increase the temperature.【Conclusion】As the tested corn-straw derived biochar can strongly absorb the CTC and the desorption rate was relative low, so that the tested corn-straw derived biochar has a good removal efficiency of exogenous CTC in aqueous phase.

Key words: chlortetracycline , biochar , retention , desorption

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