Scientia Agricultura Sinica ›› 2012, Vol. 45 ›› Issue (4): 743-751.doi: 10.3864/j.issn.0578-1752.2012.04.015

• STORAGE·FRESH-KEEPING·PROCESSING • Previous Articles     Next Articles

Effects of the Residues of Agricultural Chemicals in Grapes on Winemaking

 LI  Ji-Ming, SI  He-Yun, YU  Ying, DUAN  Hui, LIANG  Dong-Mei, JIANG  Wen-Guang, LI  Xue-Hui   

  1. 1.张裕集团有限公司技术中心，山东烟台 264001
  • Received:2011-08-10 Online:2012-02-15 Published:2011-12-23

PDF

1640

Cited

12

Abstract: 【Objective】The residues of agricultural chemicals in grapes and wines from three grapevine varieties in Yantai region were monitored, with the aim to investigate the influence of agricultural chemicals on grape fermentation and wine quality.【Method】The organophosphorous and organochlorine pesticide residues in grape and wine were determined by using gas chromatography-flame photometric detection (GC-FPD) and gas chromatography-electron capture detector (GC-ECD), respectively. 【Result】The striazolone was detected in all grape samples of Cabernet Sauvignon and Chardonnay from four areas in Yantai. Its average content was 71.09 µg•kg-1. Benzene hexachloride was found in Chardonnay from plot 1 and in Cabernet Sauvignon from plot 3, with the concentrations of 2.23 µg•kg-1 and 4.86 µg•kg-1, respectively. Cyhalothrin was found in two grape cultivars from plot 2 and 3, and its concentration ranged from 2.36 µg•kg-1 to 7.51 µg•kg-1 with a mean content of 4.28 µg•kg-1. Among the four agricultural chemicals tested, miconazole nitrate had the strongest inhibitory effect, because the alcoholic fermentation ceased when the amount of this compound exceeded 0.20 g•kg-1. After wine-making, the content of residues of agricultural chemicals in wines were quantified, and benzene hexachloride presented the highest transfer rate from grape to wine (32.14%), whereas chlorothalonil, cyhalothrin and triadimefon showed the values never higher than 0.7%. 【Conclusion】 The residues of agricultural chemicals in wine grapes in Yantai region fulfilled the related requirements. The residues of agricultural chemicals had some effects on fermentation process and generate off-flavors that will negatively affect the sensory of wines. However, the content of residues were reduced evidently during winemaking, and varied significantly in the final products depending on the characteristics of agricultural chemicals.

Key words: grape, wine, agricultural chemical, sensory quality

[1]赵红刚. 果树生产中农药的污染问题及治理对策. 烟台果树, 2007(4): 4-5.

Zhao H G. The problem of pesticides residue in fruit tree production and its countermeasures. Yantai Fruits, 2007(4): 4-5. (in Chinese)

[2]李海兰, 叶慧琼, 王忠跃, 战吉宬, 黄卫东. 3种杀真菌剂对葡萄酒酿酒酵母生长和发酵性能的影响. 中外葡萄与葡萄酒, 2009(7): 5-9.

Li H L, Ye H Q, Wang Z Y, Zhan J C, Huang W D. Influence of three fungicides on growth and fermentability of wine yeast. Sino-Overseas Grapevine & Wine, 2009(7): 5-9. (in Chinese)

[3]淑  英, 王  华, 王贞强. 我国和CAC葡萄农药残留标准比较. 中外葡萄与葡萄酒, 2005(3): 45-47.

Shu Y, Wang H, Wang Z Q. Compare the standards of MRLs on grape between China and CAC. Sino-Overseas Grapevine & Wine, 2005(3): 45-47. (in Chinese)

[4]赖穗春, 王富华, 邓义才, 杜应琼, 徐爱平, 黄洁晖. 国内外农药残留分析技术研究现状与发展. 广东农业科学, 2006(1):76-77.

Lai S C, Wang F H, Deng Y C, Du Y Q, Xu A P, Huang J H. Actual state and development of domestic and foreign techniques for analysis of agricultural chemicals residue. Guangdong Agricultural Sciences, 2006(1):76-77.(in Chinese)

[5]淑  英, 王  华, 王贞强. 葡萄酒中农药残留的色谱分析法研究进展. 中国农业通报, 2005, 21(8):65-69.

Shu Y, Wang H, Wang Z Q. Advances of studies on analytical methods for pesticide residues in wine with chromatographic. Chinese Agricultural Science Bulletin, 2005, 21(8): 65-69. (in Chinese)

[6]王金芳, 栾  鸾, 王正全, 江树人, 潘灿平. 微液液提取或固相微萃取法净化、气相色谱-质谱联用检测葡萄酒中19种农药残留. 分析化学, 2007, 35(10): 1430-1434.

Wang J F, Luan Y, Wang Z Q, Jiang C R, Pan C P. Determination of 19 multi-residue pesticides in grape wine by gas chromatography-mass spectrometry with micro liquid-liquid extraction and solid phase extraction. Chinese Journal of Analytical Chemistry, 2007, 35(10): 1430-1434. (in Chinese)

[7]González-Rodríguez R M, Cancho-Grande B, Torrado-Agrasar A, Simal-Gándara J, Mazaira-Pérez J. Evolution of Tebuconazole Residues through the winemaking process of Mencia grape. Food Chemistry, 2009, 117: 529-537.

[8]Cus F, Cesnik H B, Bolta S V, Gregorcic A. Pesticide residues in grapes and during vinification process. Food Control, 2010, 21 (11): 1512-1518.

[9]Cabras P, Garau V L, Pirisi F M, Cubeddu M, Cabitza F, Spanedda L. Fate of some insecticides from vine to wine. Journal of Agricultural and Food Chemistry, 1995, 43(10): 2613-2615.

[10]Fernández M J, Oliva J, Barba A, Cámara M A. Effects of clarification and filtration processes on the removal of fungicides residues in red wine (Var Monastrell). Journal of Agricultural and Food Chemistry, 2005, 53(15): 6156-6161.

[11]González-Rodríguez R M, Noguerol-Pato R, González-Barreiro C, Cancho-Grande B, Simal-Gándara J. Application of new fungicides under good agricultural practices and their effects on the volatile profile of white wines. Food Research International, 2011, 44:397-403.

[12]李  华. 葡萄酒工艺学. 北京: 科学出版社, 2008.

Li H. Modern Enology. Beijing: Science Press, 2008. (in Chinese)

[13]中华人民共和国农业部. 绿色食品——葡萄（NY/T428—2000）. 2000.

Ministry of Agriculture of the People's Republic of China. Green food-Grape (NY/T428—2000). 2000. (in Chinese)

[14]中华人民共和国国家质量监督检验检疫总局. 农产品安全质量无公害水果安全要求 (GB18406.2—2001). 2001.

General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China (AQSIQ). Safety qualification for agricultural product-Safety requirements for non- environmental pollution fruit (GB18406.2—2001). 2001. (in Chinese)

[15]中华人民共和国卫生部, 中国国家标准化管理委员会. 食品中农药最大残留限量(GB 2763—2005). 2005.

Ministry of Public Health of the People's Republic of China, Sac Standardization Administration of China. Maximum residue limits for pesticides in food (GB 2763—2005). 2005. (in Chinese)

[16]Calhelha R C, Andrade J V, Ferreira I C, Estevinho L M. Toxicity effects of fungicide residues on the wine-producing process. Food Microbiology, 2006, 23(4):393-398.

[17]Paolo C, Alberto A, Vincenzo LG, Melis M, Pirisi F M, Farris G, Sotgiu C, Minelli E V. Persistence and metabolism of folpet in grapes and wine. Journal of Agricultural and Food Chemistry, 1997, 45(2): 476-479.

[18]Polsinelli M, Vandini C. Studies on the effects of fungicides on wine yeasts. Vignevini, 2003, 30(11): 137-139.

[19]De Melo Abreu S, Caboni P, Pirisi F M, Cabras P, Alves A, Garau V L. Residues of the fungicide famoxadone in grape and its fate during wine production. Food Additives and Contaminants, 2006, 23(3): 289-294.

[20]Ruediger G, Sas A, Pollnitz A P, Pardon K H, Godden P. Removal of pesticides from red and white wine by the use of fining and filter agents. Australian Journal of Grape and Wine Research, 2004, 10(1): 8-16.

[21]Soles G J, Goldberg D M. Pesticide residues in unfermented grape juice and raw wines: A 5-year survey of more 3000 products. Journal of Wine Research, 2000, 11(3):197-207.

[22]Cabras P, Angioni A, Garau V L, Pirisi F M, Farris G A, Madau G, Emonti G. Pesticides in fermentative processes of wine. Journal of Agricultural and Food Chemistry, 1999, 47(9):3854-3857.

[23]The codex commission pesticide residues (CCPR). Codex maximum residue limits for pesticides (CAC/MRL01-2001). 2001.

[24]刘  文, 云振宇, 王乃铝, 许建军, 李  强, 蔡晓湛. 我国与国际食品法典委员会（CAC）食品中农药最大残留量标准的对比分析研究. 食品工业科技, 2009, 30(6): 380-382.

Liu W, Yun Z Y, Wang N L, Xu J J, Li Q, Cai X Z. Study in comparison and analysis on standards of pesticide maximum residue limits in food between international codex alimentarius commission and China national standards. Science and Technology of Food Industry, 2009, 30(6): 380-382. (in Chinese)

[25]The Australian Wine Research Institute. Agrochemicals registered for use in Australian viticulture. 2010. http://www.awri.com.au/industry% 5Fsupport/viticulture/agrochemicals/mrls/search.asp, 2011-01-10.
[1] ZHU JiaWei, GUAN Xuan, RAO BoHan, LIU XiuHai, FAN GuoYuan, WU Yun, TAO YongSheng. Effect of Alcohol-Malolactic Three-Strain Co-Fermentation Mediated by Lactobacillus brevis LB-21 on the Color of Dry Red Wine [J]. Scientia Agricultura Sinica, 2026, 59(5): 1101-1110.
[2] ZHANG MengBo, TAN HongBing, SHEN Tian, XU MeiLong, ZHOU XinMing, FANG YuLin, JU YanLun. Effects of Different Irrigation Amounts and Anti-transpirant Treatments on Wine Quality [J]. Scientia Agricultura Sinica, 2026, 59(2): 413-426.
[3] FENG WeiQing, NI YuanQian, FEI Teng, LI YouMei, XIE ZhaoSen. Differences in Vascular Bundle Morphological Structure, Distribution, and Water Transport Function in Grape Fruits of Different Shapes [J]. Scientia Agricultura Sinica, 2026, 59(1): 161-178.
[4] WANG SiQi, ZOU LiRen, BAI RuiWen, YAN Ke, WANG SiYang, QI XiaoGuang, SHEN HaiLin, WEN JingHui. Screening of Key Genes Related to Gibberellic Acid Regulation of Rachis Hardening in Honey Grapes [J]. Scientia Agricultura Sinica, 2026, 59(1): 179-189.
[5] TAN XiBei, LAN XuYing, LIU ChongHuai, FAN XiuCai, JIANG JianFu, SUN Lei, LI Peng, YU ShuXin, ZHANG Ying. Changes of Secondary Metabolites in Grapes with Different Resistance Levels in Response to White Rot Infection [J]. Scientia Agricultura Sinica, 2025, 58(9): 1767-1778.
[6] TANG XueShen, DANG ShiZhuo, ZHOU Juan, LI JiaHao, LI MeiHua, HU Hao, ZHANG YaHong. Analysis of VvBES1-1 Involvement in Flower Bud Differentiation of Red Globe Grape Based on Red and Blue Light Regulation [J]. Scientia Agricultura Sinica, 2025, 58(8): 1650-1662.
[7] YANG CaiLi, LI YongZhou, HE LiangLiang, SONG YinHua, ZHANG Peng, LIU ZhaoXian, LI PengHui, LIU SanJun. Genome-Wide Identification and Analysis of TPS Gene Family and Functional Verification of VvTPS4 in the Formation of Monoterpenes in Grape [J]. Scientia Agricultura Sinica, 2025, 58(7): 1397-1417.
[8] GUO AoLin, LIN JunXuan, LAI GongTi, HE LiYuan, CHE JianMei, PAN Ruo, YANG FangXue, HUANG YuJi, CHEN GuiXin, LAI ChengChun. Effect of VdF3′5′H2 Overexpression on the Accumulation of Anthocyanin Composition in Spine Grape Cells [J]. Scientia Agricultura Sinica, 2025, 58(4): 802-818.
[9] ZHANG XiangKun, LI JiaYing, QIAO RuMeng, HE JingLei, WANG Li, SHI XiaoXin, DU GuoQiang. Effects of GFabV Under Different Zn Levels on Photosynthetic Efficiency and Photosynthesis-Related Gene Expression of ‘Shine Muscat’ Grapevine [J]. Scientia Agricultura Sinica, 2025, 58(24): 5190-5200.
[10] WANG Di, HAN ShouAn, ZHANG Wen, WANG Min, SHI HuiDong, ZHU XueHui, BAI ShiJian, LIU XuPeng, TIAN Jia, XIE Hui. Effects of Different Plant Growth Regulators on Fruit and Raisin Quality of Thompson Seedless Grapes [J]. Scientia Agricultura Sinica, 2025, 58(18): 3767-3782.
[11] YU Huan, LIN Ling, GUO RongRong, CAO XiongJun, WANG Bo, FANG JingGui, XIE ShuYu, HUANG XiaoYun, HAN JiaYu, BAI XianJin. Investigation and Evaluation of Inflorescence Attachment and Quality of Grape Germplasm Resources in The Hot Zone Guangxi [J]. Scientia Agricultura Sinica, 2025, 58(17): 3503-3515.
[12] HE XiaoPing, ZHANG YuanFeng, LIU XueMin, HUANG Li, WENG ChangJiang. Preparation of Monoclonal Antibody Against African Swine Fever Virus pD345L Protein and Identification of Its Epitope [J]. Scientia Agricultura Sinica, 2025, 58(16): 3345-3356.
[13] WANG HuiLing, ZHANG YingYing, YAN AiLing, WANG XiaoYue, LIU ZhenHua, REN JianCheng, XU HaiYing, SUN Lei. Multi-Omics Analysis Reveals the Changes of Monoterpenes and Anthocyanins Accumulation During Veraison in Red Muscat-Type Grape [J]. Scientia Agricultura Sinica, 2025, 58(13): 2645-2662.
[14] CAO XiongJun, WANG Bo, HAN JiaYu, LIAO YongFeng, XIE ShuYu, BAI Yang, HUANG XiaoYun, LU Li, HUANG QiuMi, JIANG ChunFen, PAN FengPing, BAI XianJin. Research and Practice on High Photosynthetic Efficiency Breeding of Grapes in Hot Climate Regions [J]. Scientia Agricultura Sinica, 2025, 58(10): 1994-2007.
[15] DONG Jie, ZHANG Peng, LI WangZe, LI HeFang, ZHOU GuoChao, CHEN KeQin, FANG YuLin, ZHANG KeKun. Effects of Seedlessness and Swelling Treatments Based on GA3 and CPPU on the Fruit Quality of 'Shine Muscat' Grapes [J]. Scientia Agricultura Sinica, 2025, 58(10): 2008-2021.
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed   
No Suggested Reading articles found!
京ICP备09089781号-30
Copyright 2018 © Editorial office of Scientia Agricultura Sinica
Tel: 86-010-82106279    E-mail: zgnykx@mail.caas.net.cn
Supported by Beijing Magtech Co.Ltd