近红外光谱对小麦产地来源的判别分析

doi:10.3864/j.issn.0578-1752.2011.07.018

摘要/Abstract

摘要： 【目的】对不同产地来源小麦的近红外光谱进行判别分析，为小麦的产地鉴别提供一种新方法。【方法】应用近红外光谱分析仪检测2007/2008年度和2008/2009年度中国小麦主产区河北省、河南省、山东省和陕西省共240份小麦籽粒样品，对近红外光谱数据分别进行均值标准化、一阶求导和多元散射校正(MSC)处理后，利用偏最小二乘判别分析法(DPLS)分析预处理后的数据。【结果】2007/2008年度小麦籽粒样品总体正确判别率为87.5%，2008/2009年度样品总体正确判别率为91.7%；用2007/2008年度样品所建模型来预测2008/2009年度的样品，结果总体正确判别率为48.3%；两年样品混合后，总体正确判别率为82.5%。【结论】不同地域来源小麦的近红外光谱特征有显著差异，但其受品种和年际因素影响较大，判别模型的稳定性有待进一步提高。

关键词: 小麦 , 产地 , 近红外光谱 , DPLS

Abstract: 【Objective】 A new method was developed for identification of the geographical origins of wheat with discriminant analysis by near infrared reflectance spectroscopy (NIRS). 【Method】A total of 240 wheat kernel samples collected in 2007-2008 and 2008-2009 from Hebei, Henan, Shandong and Shaanxi provinces of China were analyzed by NIRS. After normalization, first derivative and multiplicative scattering correction (MSC) pre-treatment of wheat kernel spectral data, discriminant partial least squares analysis (DPLS) was applied to classify the geographical origins of these samples. 【Result】 There were 87.5% and 91.7% of wheat kernel samples collected in 2007-2008 and 2008-2009 were correctly classified respectively, the total correct classification of 48.3% was achieved by DPLS models developed using the samples collected in 2007-2008 harvest period to predict the geographical origin of the samples collected in 2008-2009 harvest period, and 82.5% were correctly classified by DPLS models developed using 2/3 of the total sample set to test the remaining 1/3 of the samples. 【Conclusion】There are significant differences among near infrared spectra of wheat from different origins which are influenced mainly by the varieties and annual changes, and the stability of DPLS models developed has to be improved further.

Key words: wheat , geographical origin , NIRS , DPLS

赵海燕，郭波莉，魏益民，张波，孙淑敏，严军辉，张磊. 近红外光谱对小麦产地来源的判别分析[J]. 中国农业科学, 2011, 44(7): 1451-1456.

ZHAO Hai-yan, GUO Bo-li, WEI Yi-min, ZHANG Bo, SUN Shu-min, YAN Jun-hui, ZHANG Lei. Identification of Geographical Origins of Wheat with Discriminant Analysis by Near Infrared Spectroscopy[J]. Scientia Agricultura Sinica, 2011, 44(7): 1451-1456.

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参考文献

[1]32002R0178 (EC 178/2002), Regulation (EC) No 178/2002 of the European Parliament and of the Council of 28 January 2002 laying down the general principles and requirements of food law, establishing the European Food Safety Authority and laying down procedures in matters of food safety[S].
[2]H.R.2749 RFS, Food Safety Enhancement Act of 2009[S].
[3]中华人民共和国主席令第9号. 中华人民共和国食品安全法[S].
Article 9 of a presidential order of the People's Republic of China. Food safety of the People's Republic of China[S]. (in Chinese)
[4]GB 1351-2008, 小麦[S].
GB 1351-2008, Wheat[S]. (in Chinese)
[5]Osborne B G, Fearn T, Hindle P H. Practical NIR Spectroscopy with Applications in Food and Beverage Analysis. London: Longman Scientific and Technical, 1993.
[6]Rharrabti Y, Royo C, Villegas D, Aparicio N, García del Moral L F. Durum wheat quality in Mediterranean environments. I. Quality expression under different zones, latitudes and water regimes across Spain. Field Crops Research, 2003, 80: 123-131.
[7]Tribio E, Abad A, Michelena A, Lloveras J, Ollier J L, Daniel C. Environmental effects on the quality of two wheat genotypes. I. Quantitative and qualitative variation of storage proteins. European Journal of Agronomy, 2000, 13:47-64.
[8]赵春, 宁堂原, 焦念元, 韩宾, 李增嘉. 基因型与环境对小麦籽粒蛋白质和淀粉品质的影响. 应用生态学报, 2005, 16(7): 1257-1260.
Zhao C, Ning T Y, Jiao N Y, Han B, Li Z J. Effects of genotype and environment on protein and starch quality of wheat grain. Chinese Journal Applied Ecology, 2005, 16: 1257-1260. (in Chinese)
[9]Pillonel L, Luginbuhl W, Picque D, Schaller E, Tabacchi R, Bosset J O. Analytical methods for the determination of the geographic origin of Emmental cheese: mid- and near-infrared spectroscopy. European Food Research and Technology, 2003, 216:174-178.
[10]Karoui R, Dufour E, Pillonel L, Schaller E, Picque D, Cattenoz T, Bosset J O. The potential of combined infrared and fluorescence spectroscopies as a method of determination of the geographic origin of Emmental cheeses. International Dairy Journal, 2005, 15: 287-298.
[11]Galtier O, Dupuy N, Dréau Y Le, Ollivier D, Pinatel C, Kister J, Artaud J. Geographic origins and compositions of virgin olive oils determinated by chemometric analysis of NIR spectra. Analytica Chimica Acta, 2007, 595: 136-144.
[12]Casale M, Casolino C, Oliveri P, Forina M. The potential of coupling information using three analytical techniques for identifying the geographical origin of Liguria extra virgin olive oil. Food Chemistry, 2010, 118: 163-170.
[13]Woodcock T, Downey G, O’Donnell C P. Near infrared spectral fingerprinting for confirmation of claimed PDO provenance of honey. Food Chemistry, 2009, 114: 742-746.
[14]Osborne B G, Mertens B, Thompson M, Fearn T. The authentication of Basmati rice using near infrared spectroscopy. Journal of Near Infrared Spectroscopy, 1993, 1: 77-83.
[15]Yu H Y, Zhou Y, Fu X P, Xie L J, Ying Y B. Discrimination between Chinese rice wines of different geographical origins by NIRS and AAS. European Food Research and Technology, 2007, 225: 313-320.
[16]李勇, 魏益民, 潘家荣, 郭波莉. 基于FTIR指纹光谱的牛肉产地溯源技术研究. 光谱学与光谱分析, 2009, 29(3): 647-651.
Li Y, Wei Y M, Pan J R, Guo B L. Determination of geographical origin of beef based on FTIR spectroscopy analysis. Spectroscopy and Spectral Analysis, 2009, 29: 647-651. (in Chinese)
[17]Armanino C, Acutis R D, Festa M R. Wheat lipids to discriminate species, varieties, geographical origins and crop years. Analytica Chimica Acta, 2002, 454: 315-326.
[18]Armaninoa C, Festab M R. Characterization of wheat by four analytical parameters-A chemometric study. Analytica Chimica Acta, 1996, 331: 43-51.
[19]Branch S, Burke S, Evans P, Fairman B, Briche C S J W. A preliminary study in determining the geographical origin of wheat using isotope ratio inductively coupled plasma mass spectrometry with 13C, 15N mass spectrometry. Journal of Analytical Atomic Spectrometry, 2003, 18: 17–22.
[20]Miralbés C. Discrimination of European wheat varieties using near infrared reflectance spectroscopy. Food Chemistry, 2008, 106: 386-389.
[21]Delwiche S R. Single wheat kernel analysis by near-infrared transmittance: Protein content. Cereal Chemistry, 1995, 72: 11-16.
[22]Delwiche S R. Protein content of single kernels of wheat by near infrared reflectance spectroscopy. Journal of Cereal Science, 1998, 27: 241-254.
[23]Delwiche R S, Graybosch R A, Peterson C J. Predicting protein composition, biochemical properties, and dough-handling properties of hard red winter wheat by near-infrared reflectance. Cereal Chemistry, 1998, 75: 412-416.
[24]Miralbés C. Prediction chemical composition and alveograph parameters on wheat by near-infrared transmittance spectroscopy. Journal of Agricultural and Food Chemistry, 2003, 51: 6335-6339.
[25]严衍禄. 近红外光谱分析基础与应用. 北京: 中国轻工业出版社, 2005: 38.
Yan Y L. Basics and Application of Near Infrared Spectral Analysis. Beijing: China Light Industry Press, 2005: 38. (in Chinese)
[26]潘洁, 姜东, 戴廷波, 兰涛, 曹卫星. 不同生态环境与播种期下小麦籽粒品质变异规律的研究. 植物生态学报, 2005, 29(3): 467-473.
Pan J, Jiang D, Dai T B, Lan T, Cao W X. Variation in wheat grain quality grown under different climatic conditions with different sowing dates. Acta Phytoecologia Sinica, 2005, 29: 467-473. (in Chinese)
[27]Xu Z Z, Yu Z W, Wang D, Zhang Y L. Nitrogen accumulation and translocation for winter wheat under different irrigation regimes. Journal of Agronomy and Crop Science, 2005, 191: 439-449.
[28]Cooper M, Woodruff D R, Phillips I G, Basford K E, Gilmour A R. Genotype-by-management interactions for grain yield and grain protein concentration of wheat. Field Crops Research, 2001, 69: 47-67.
[29]赵秀兰. 春小麦灌浆期籽粒沉淀值动态变化及氮磷肥与播期的影响. 应用生态学报, 2006, 17(4): 640-646.
Zhao X L. Effects of nitrogen and phosphorus fertilization and sowing date on dynamic changes of grain sedimentation value during grain filling stage of spring wheat. Chinese Journal Applied Ecology, 2006, 17(4): 640-646. (in Chinese)