大蒜中有机硫化合物及其分析方法

doi:10.3864/j.issn.0578-1752.2019.18.012

Abstract

Abstract:

Garlic is a kind of widely planted agricultural product in China, which has plenty of nutritional and healthy functions, such as antibacterial, anti-inflammatory, and anti-oxidation. These functions are mainly attributed to the organic sulfur compounds, including the flavor precursors, thiosulfinates and thioether volatile compounds. The organic sulfur compounds either have its own biological activities, or multiple compounds work together to produce the same physiological effect. However, considering the poor stability and property diversity of the organic sulfur compounds, the analysis of organic sulfur compounds remains a big challenge. Existing reports are mainly on the determination of several compounds or one group of compounds, and there has been no comprehensive analysis of the organic sulfur compounds in garlic yet. Therefore, in the present review, the analysis methods of the main flavor precursors, thiosulfinates and thioether volatile compounds in garlic were separately discussed and summarized, including the sample pretreatment and detection methods.

Key words: garlic, organic sulfur compounds, analytical methods, nutritional ingredient

WENG Rui,SHENG XiaoJing,LIU PingXiang,ZHANG JiGuang,QIU Jing,QIAN YongZhong. Analytical Methods of the Organic Sulfur Compounds in Garlic[J].Scientia Agricultura Sinica, 2019, 52(18): 3199-3206.

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Figures/Tables 2

Table 1

The organic sulfur compounds of garlic"

类别 Category	名称 Name	CAS号 CAS number
风味前体化合物 Flavor precursor	蒜氨酸 Alliin	556-27-4
	甲基蒜氨酸 Methiin	32726-14-0
	异蒜氨酸 Isoalliin	23315-20-0
	环蒜氨酸 Cycloalliin	455-41-4
	S-甲基-L-半胱氨酸 S-Methyl-L-cysteine (SMC)	1187-84-4
	S-丙烯基-L-半胱氨酸 S-(trans-1-Propenyl)-L-cysteine (SPC)	-
	S-烯丙基-L-半胱氨酸 S-Allyl-L-cysteine (SAC)	21593-77-1
	γ-L-谷氨酰-S-甲基-L-半胱氨酸 γ-L-Glutamyl-S-methyl-L-cysteine (GSMC)	-
	γ-L-谷氨酰-S-丙烯基-L-半胱氨酸 γ-L-Glutamyl-S-(trans-1-propenyl)-L-cysteine (GSPC)	-
	γ-L-谷氨酰-S-烯丙基-L-半胱氨酸 γ-L-Glutamyl-S-allyl-L-cysteine (GSAC)	91216-95-4
	γ-谷氨酸-半胱氨酸 γ-Glutamyl cycteine	636-58-8
硫代亚磺酸酯 Thiosulfinate	γ-谷氨酰-S-甲基-L-半胱氨酸亚砜 γ-Glutamyl-S-methyl-L-cysteine sulfoxide	-
	γ-谷氨酰-S-丙烯基-L-半胱氨酸亚砜 γ-Glutamyl-S-(1-propenyl)-L-cysteine sulfoxide	-
	γ-谷氨酰-S-烯丙基-L-半胱氨酸亚砜 γ-Glutamyl-S-allyl-L-cysteine sulfoxide	-
	甲基烯丙基硫代亚磺酸酯 Methyl allyl thiosulfinate	-
	甲基丙烯基硫代亚磺酸酯 Methyl propenyl thiosulfinate	-
	丙烯基甲基硫代亚磺酸酯 Propenyl methyl thiosulfinate	-
	丙烯基烯丙基硫代亚磺酸酯 Propenyl allyl thiosulfinate	-
	烯丙基甲基硫代亚磺酸酯 Allyl methyl thiosulfinate	-
	烯丙基丙烯基硫代亚磺酸酯 Allyl propenyl thiosulfinate	-
	二甲基硫代亚磺酸酯 Dimethyl thiosulfinate	13882-12-7
	二丙烯基硫代亚磺酸酯 Dipropenyl thiosulfinate	-
	二烯丙基硫代亚磺酸酯（大蒜素） Diallyl thiosulfinate (Allicin)	539-86-6
硫醚类挥发性有机硫化合物 Thioether volatile compound	烯丙基甲基一硫化物 Allyl methvl sulfide (AMS)	10152-76-8
	烯丙基甲基二硫化物 Allyl methyl disulfide (AMD)	2179-58-0
	烯丙基甲基三硫化物 Allyl methyl trisulfide (MATS)	34135-85-8
	烯丙基甲基四硫化物 Allyl methyl tetrasulfide (MATTS)	-
	二烯丙基一硫化物 Diallyl sulfide (DAS)	592-88-1
	二烯丙基二硫化物 Diallyl disulfide (DADS)	2179-57-9
	二烯丙基三硫化物（大蒜新素） Diallyl trisulfide (DATS)	2050-87-5
	二烯丙基四硫化物 Diallyl tetrasulfide (DATTS)	2444-49-7
	二甲基一硫化物 Methyl sulfide (DMS)	75-18-3
	二甲基二硫化物 Dimethyl disulfide (DMDS)	624-92-0
	二甲基三硫化物 Dimethyl trisulfide (DMTS)	3658-80-8
	二丙基二硫化物 Propyl disulfide (DPDS)	629-19-6
	甲基丙基二硫化物 Methyl propyl disulfide (PMDS)	2179-60-4
	二苯基二硫化物 Diphenyl disulphide	882-33-7
	E-阿霍烯 E-Ajoene	92285-01-3
	Z-阿霍烯 Z-Ajoene	92285-00-2
	2-乙烯基-4H-l,3-二噻烯 2-Vinyl-4H-1,3-dithiin	80028-57-5
	3-乙烯基-4H-1,2-二噻烯 3-Vinyl-4H-1,2-dithiin	62488-53-3

Table 1

Fig. 1

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