Scientia Agricultura Sinica ›› 2024, Vol. 57 ›› Issue (17): 3469-3481.doi: 10.3864/j.issn.0578-1752.2024.17.012

• FOOD SCIENCE AND ENGINEERING • Previous Articles     Next Articles

Research Progress on Adsorption Properties of Solid Particles with Different Morphologies at the Interface of Pickering Emulsions

LU LiRong(), YAO XiaoLin(), LI Dan, WEI XiangYing, YUE Juan, YI GaoYang   

  1. College of Food Science and Engineering, Shaanxi University of Science and Technology, Xi’an 710021
  • Received:2024-04-08 Accepted:2024-06-24 Online:2024-09-01 Published:2024-09-04
  • Contact: YAO XiaoLin

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Abstract:

Pickering emulsions represent a novel type of emulsion that employs solid particles as stabilizers. Solid particles can be tightly arranged at the oil-water interface by irreversible adsorption to form a monolayer or multilayer film, providing a spatial physical barrier for droplets. Compared with traditional emulsions, Pickering emulsions have attracted wide attention due to their advantages of high stability, low toxicity and low cost. The stability of Pickering emulsion is affected by many factors, such as solid particle properties, concentration, pH and preparation method, etc. Among them, the morphology of solid particles is one of the important factors that determines the interface adsorption behavior and the stabilization ability of emulsion. The different morphology of the solid particles leads to different ways of stabilizing the emulsion at the oil-water interface, mainly includes electrostatic interaction, capillary force, and mutual entanglement to form three-dimensional network structure. However, there is currently no systematic summary on the effects of solid particles with different morphologies on the interfacial adsorption characteristics of Pickering emulsions. Based on this, this review summarized the types of solid particles with different morphologies used to stabilize Pickering emulsions at home and abroad in recent years, including spherical, rod-like, thread-like, flaky, cubic, nanotube, dumbbell, ellipsoid and disc-like, etc. It focused on their interfacial adsorption properties for stabilizing Pickering emulsions, such as adsorption activity, arrangement and assembly behavior, inter-particle interactions and emulsion viscosity, etc. Based on the special interfacial adsorption properties of Pickering emulsions, the applications of Pickering emulsions in food fields such as active component encapsulation and delivery, lipid substitution, interfacial catalysis, antimicrobial and so on were reviewed. Furthermore, the study discussed the problems in the study of Pickering emulsions stabilized by non-spherical solid particles, and analyzed the development potential for active component encapsulation and delivery. The review provided the reference for the in-depth research and application of Pickering emulsions stabilized by solid particles with different morphologies.

Key words: solid particles, different morphologies, Pickering emulsions, interfacial adsorption properties, food field

Fig. 1

Mechanism diagram of Pickering emulsion stabilized by solid particles A: Steric hindrance; B: Electrostatic repulsion; C: The interaction between particles forms a three-dimensional network"

Fig. 2

Interfacial adsorption diagram of solid particles with different morphologies"

Table 1

Solid particles with different morphologies and their main action modes for stabilizing emulsions"

形貌
Morphology		 固体颗粒
Solid particles		 稳定乳液的主要作用方式
Main action modes for stabilizing emulsions		 参考文献
Reference
球形
Spherical		 SiO2、聚苯乙烯微球、球形纤维素纳米晶、TiO2、Fe2O3
SiO2, polystyrene particles, spherical cellulose nanocrystals, TiO2, Fe2O3		 静电相互作用、范德华力、空间位阻
Electrostatic interaction, van der Waals force, steric hindrance		 [10-11]
棒状
Rod-like		 棒状纤维素纳米纤维、棒状二氧化硅
Cellulose nanofiber, rod-like silica colloids		 毛细管力、静电相互作用、界面定向排列
Capillary force, electrostatic interaction, interface directional arrangement		 [12⇓-14]
线状
Thread-like		 线状二氧化硅纳米颗粒、蛋白微纤维
Thread-like mesoporous silica nanoparticles, protein microfibers		 相互缠结形成三维网络结构
Intertwined to form a three-dimensional network structure		 [15-16]
片状
Flaky		 蒙脱土、高岭土、锂皂石、片状双金属氢氧化物、氧化石墨烯薄片等
Montmorillonite, kaolin, laponite, layered double hydroxide compounds, graphene oxide		 界面贴合吸附、降低界面张力
Interface adhesion adsorption, reduce the interfacial tension		 [17-18]
立方体
Cubic		 赤铁矿微粒、碳酸钙颗粒、笼形二氧化硅立方体纳米粒子
Hematite microparticles, calcium carbonate particles, cage-shaped silica cubic nanoparticle		 界面不可逆吸附、单层形式组装
Interface irreversible adsorption, monolayer assembly		 [19-20]
纳米管
Nanotube		 碳纳米管、埃洛石纳米管
Carbon nanotubes, halloysite nanotubes		 界面自组装、毛细管力
Interface self-assembly, capillary force		 [21-22]
其他
Others		 哑铃状、椭圆状、盘状等
Dumbbell, ellipsoid, disc-like, etc		 静电相互作用、强粘附性等
Electrostatic interaction, strong adhesion, etc		 [23-24]

Fig. 3

Contact angle diagram of spherical solid particles at the oil-water interface"

Fig. 4

Interfacial adsorption of Pickering emulsions stabilized by nanorods with different aspect ratios"

Fig. 5

Application of Pickering emulsion stabilized by solid particles with different morphologies in food field"

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doi: S0141-8130(17)32765-4 pmid: 29414733
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