燃煤烟气脱硫石膏农用的环境安全风险

doi:10.3864/j.issn.0578-1752.2018.05.011

Abstract

Abstract: Utilization of flue gas desulfurization (FGD) gypsum in China to improve alkaline soils started in the late 1990s. The FGD gypsum is a kind of desulfurized waste residue from power plant. It is an industrial by-product gypsum obtained by desulfurization and purification of flue gas produced by sulfur bearing fuel (mainly coal). With the increasing of installation of flue gas pollution control system, such as dust removal, desulfurization and denitrification in coal-fired power plants in China, more and more desulfurization by-product gypsum will be produced while reducing SO₂ emission and other harmful gases in the process of coal combustion. The utilization of FGD gypsum has attracted more attention for solving the problem with increased disposal of desulfurization residues in power plants. Because the nature of FGD gypsum is similar to that of natural gypsum, some researchers have tried to use it instead of natural gypsum in the improvement of saline alkali land. However, since some enterprises introduced flue gas purification technology and synergistic mercury removal process, several hazardous pollutants in coal would inevitably transfer into FGD by-products (FGD gypsum and fly-ash). The process of FGD and synergistic mercury removal causes the enrichment of several hazardous pollutants in FGD gypsum (mainly Hg, F, Cl, and Se), and in FGD fly-ash (mainly As, Cd, Cr, Cu, Ni, Pb, and Zn). Research results indicated that the enrichment of hazardous pollutants could result in high levels of hazardous pollutants (especially Hg, Se, F and Cl) in some FGD gypsum in China, inordinately beyond the limits of Environmental Quality Standards for Soils and the limits of Environmental Quality Standards for Ground Water. In order to ensure soil health, food safety, and environmental quality, it was suggested that those FGD by-products without any harmless treatment of pollutants should not be allowed to use as for soil remediation or conditioning directly into the farmlands by solid waste disposal methods; especially material source and technology of desulfurization, application rate in farmland and long-term environmental safety risk should be concerted, to prevent hazardous pollutants from entering food chain and harming to human health.

Key words: industrial solid wastes, environmental safety risk, soil pollution, flue gas desulfurization gypsum, heavy metals

WANG XiaoBin, YAN Xiang, LI XiuYing, CAI DianXiong, LEI Mei. Environment Risk for Application of Flue Gas Desulfurization Gypsum in Soils in China[J].Scientia Agricultura Sinica, 2018, 51(5): 926-939.

0
/ / Recommend

Add to citation manager EndNote|Reference Manager|ProCite|BibTeX|RefWorks

URL: https://www.chinaagrisci.com/EN/10.3864/j.issn.0578-1752.2018.05.011

https://www.chinaagrisci.com/EN/Y2018/V51/I5/926

References

[1] 胡育骄, 王小彬, 赵全胜, 郑妍, 武雪萍, 蔡典雄, 吴会军, 许映军, 顾卫. 海冰水灌溉对不同施肥方式下土壤盐分运移及棉花的影响. 农业工程学报, 2010, 26(9): 20-27.

HU Y J, WANG X B, ZHAO Q S, ZHENG Y, WU X P, WU H J, XU Y J, GU W. Effects of sea ice water irrigation and different fertilizations on soil salinality dynamics and cotton. Transactions of the CSAE, 2010, 26(9): 20-27. (in Chinese)

[2] WANG X B, ZHAO Q S, HU Y J, ZHENG Y, WU X P, WU H J, CAI D X. LICONA M C. An alternative water source and combined agronomic practices for cotton irrigation in coastal saline soils. Irrigation Science, 2012, 30: 221-232.

[3] 曲长凤, 杨劲松, 姚荣江, 余世鹏. 不同改良剂对苏北滩涂盐碱土壤改良效果研究. 灌溉排水学报, 2012, 31(3): 21-25.

QU C F, YANG J S, YAO R J, YU S P. Effects of different soil amendments on coastal saline-alkali soil in North Jiangsu. Journal of Irrigation and Drainage, 2012, 31(3): 21-25. (in Chinese)

[4] 苗友顺, 刘卫星, 张枫叶, 石秀云, 贺群岭. 石膏不同用量对盐碱棉田改良效果的研究. 农业科技通讯, 2014(8): 114-115.

MIAO Y S, LIU W X, ZHANG F Y, SHI X Y, HE Q L. Study on effects of different amount of gypsum on saline alkali cotton field. Bulletin of Agricultural Science and Technology, 2014(8): 114-115. (in Chinese)

[5] 南江宽, 陈效民, 王晓洋, 李学林, 阿力木江, 郭志创, 王渊明. 石膏与肥料配施对滨海盐土降盐抑碱的效果研究. 南京农业大学学报, 2014, 37(4): 103-108.

NAN J K, CHEN X M, WANG X Y, LI X L, Alimujiang, GUO Z C, WANG Y M. Effects of gypsum and fertilizers amendment on reducing salinity and preventing alkalization of coastal saline soil. Journal of Nanjing Agricultural University, 2014, 37(4):103-108. (in Chinese)

[6] 李跃进, 乌力更, 芦永兴, 陈昌和, 徐旭常, 王淑娟. 燃煤烟气脱硫副产物改良碱化土壤田间试验研究. 华北农学报, 2004, 19(S1): 10-15.

LI Y J, WU L G, LU Y X, CHEN C H, XU X C, WANG S J. Amelioration of alkali-soil with the by-product of burn coal smoke desulphurization in the field. Acta Agriculturae Boreali-Sinica, 2004, 19(S1): 10-15. (in Chinese)

[7] 罗成科, 肖国举, 张峰举, 秦萍. 脱硫石膏改良中度苏打盐渍土施用量的研究. 生态与农村环境学报, 2009, 25(3): 44-48.

LUO C K, XIAO G J, ZHANG F J, QIN P. Optimal application rate of desulfurized gypsum in ameliorating soils moderate in sodic salinity. Journal of Ecology and Rural Environment, 2009, 25(3): 44-48. (in Chinese)

[8] 王昶, 黄晓明, 酒井裕司, 夏琳. 脱硫副产物在碱化土壤改良中的应用. 天津科技大学学报, 2009, 24(1): 39-43.

WANG C, HUANG X M, SAKAI Y J, XIA L. Application of by-product from flue gas desulfurization in reclamation of sodic soils. Journal of Tianjin University of Science and Technology, 2009, 24(1): 39-43. (in Chinese)

[9] 李茜, 孙兆军, 魏耀峰, 王静, 李明, 秦萍, 陈晓东. 施用脱硫废弃物对枸杞生长及重金属含量的影响. 中国农学通报, 2010, 26(11): 355-357.

LI Q, SUN Z J, WEI Y F, WANG J, LI M, QIN P, CHEN X D. Effect of by-product of flue gas desulphurization (BFGD) application on wolfberry’s growth and soil heavy metals concentration. Chinese Agricultural Science Bulletin, 2010, 26(11): 355-357. (in Chinese)

[10] 李彦, 衣怀峰, 赵博, 王淑娟, 禚玉群, 陈昌和, 徐旭常. 燃煤烟气脱硫石膏在新疆盐碱土壤改良中的应用研究. 生态环境学报, 2010, 19(7): 1682-1685.

LI Y, YI H F, ZHAO B, WANG S J, ZHUO Y Q, CHEN C H, XU X C. Study on improving Xinjiang sodic soils amelioration with desulfurized gypsum. Ecology and Environmental Sciences, 2010, 19(7): 1682-1685. (in Chinese)

[11] 王淑娟, 陈群, 李彦, 张宁, 赵博, 禚玉群, 陈昌和. 重金属在燃煤烟气脱硫石膏改良盐碱土壤中迁移的实验研究. 生态环境学报, 2013, 22(5): 851-856.

WANG S J, CHEN Q, Li Y, ZHANG N, ZHAO B, ZHUO Y Q, CHEN C H. Experimental investigation on distribution profiles of heavy metals in the desulfurization gypsum amended saline and sodic soils. Ecology and Environmental Sciences, 2013, 22(5): 851-856. (in Chinese)

[12] 李谟志, 徐彦虎, 林启美, 李贵桐, 赵小蓉. 燕麦与脱硫石膏对内蒙古河套地区盐渍化土壤肥力的影响. 中国农学通报, 2014, 30(23): 171-176.

LI M Z, XU Y H, LIN Q M, LI G T, ZHAO X R. The improvement of the Na₂SO₄ saline soil fertility with oat and desulfurization gypsum in Hetao Inner Mongolia. Chinese Agricultural Science Bulletin, 2014, 30(23): 171-176. (in Chinese)

[13] 王立志, 陈明昌, 张强, 周怀平, 郑普山, 姜森林. 脱硫石膏及改良盐碱地效果研究. 中国农学通报, 2011, 27(20): 241-245.

WANG L Z, CHEN M C, ZHANG Q Z, ZHOU H P, ZHENG P S, JIANG S L. Effects of desulfurised gypsum from coal power station on improvement of saline-alkali soil. Chinese Agricultural Science Bulletin, 2011, 27(20): 241-245. (in Chinese)

[14] 郑普山, 郝保平, 冯悦晨, 丁玉川, 李屹峰, 薛志强, 曹卫东. 不同盐碱地改良剂对土壤理化性质、紫花苜蓿生长及产量的影响. 中国生态农业学报, 2012, 20(9): 1216-1221.

ZHENG P S, HAO B P, FENG Y C, DING Y C, LI Y F, XUE Z Q, CAO W D. Effects of different saline-alkali land amendments on soil physicochemical properties and alfalfa growth and yield. Chinese Journal of Eco-Agriculture, 2012, 20(9): 1216-1221. (in Chinese)

[15] 李小平, 刘晓臣, 毛玉梅, 陈小华. 烟气脱硫石膏对围垦滩涂土壤的脱盐作用. 环境工程技术学报, 2014, 6(4): 503-507.

LI X P, LIU X C, MAO Y M, CHEN X H. Effects of flue gas desulfurization (FGD) gypsum on desalination of reclaimed tidal flat soil. Journal of Environmental Engineering Technology, 2014, 6(4): 503-507. (in Chinese)

[16] 贺坤, 李小平, 章炫耀, 张银宝. 烟气脱硫石膏对崇明滨海盐碱地理化性质及旱稻生长的影响. 西南农业学报, 2016, 29(6): 1381-1386.

HE K, LI X P, ZHANG X Y, ZHANG Y B. Effect of flue fas desulfurization gypsum (FGD-gypsum) on physical and chemical properties of soil and growth of upland rice in Chongming coastal saline soils. Southwest China Journal of Agricultural Sciences, 2016, 29(6): 1381-1386. (in Chinese)

[17] 毛玉梅, 李小平. 烟气脱硫石膏对滨海滩涂盐碱地的改良效果研究. 中国环境科学, 2016, 36(1): 225-231.

MAO Y M, LI X P. Amelioration of flue gas desulfurization gypsum on saline-sodic soil of tidal flats and its effects on plant growth. China Environmental Science, 2016, 36(1): 225-231. (in Chinese)

[18] 陈曼丁, 宋伟. 浅析脱硫石膏及再利用产品中汞的污染//中国环境科学学会学术年会论文集. 成都: 中国环境科学学会, 2014: 6136-6141.

CHEN M D, SONG W. Analysis of mercury pollution in desulfurized gypsum and its reuse products//Proceedings of Annual Conference of China Society of Environmental Science.Chengdu:China Society of Environmental Science, 2014: 6136-6141. (in Chinese)

[19] 康生. 治污又生污: 烟气脱硫技术的两大误区. 中国电力报, 2004-09-09(8).

KANG S. Pollution control and pollution: two misunderstandings of flue gas desulfurization technology. China Electric Power News, 2004-09-09(8). (in Chinese)

[20] 中华人民共和国国家环境保护部. 2017年全国大、中城市固体废物污染环境防治年报, 2017.

The Ministry of Environmental Protection of the People's Republic of China. Annual Report in 2017 on Pollution Prevention and Control of Solid Waste in Large, Medium and Large Cities in China, 2017. (in Chinese)

[21] 邓庆德, 车建炜, 岳益锋, 王群英. 影响脱硫石膏品质的因素及其改善措施. 发电与空调, 2014, 35(5): 14-17.

DENG Q D, CHE J W, YUE Y F, WANG Q Y. Influence factors on the quality of desulfurized gypsum and its control technology. Power Generation & Air Condition, 2014, 35(5): 14-17. (in Chinese)

[22] 洪燕. 中国脱硫石膏综合利用分析及建议. 中国资源综合利用, 2013, 9: 42-43.

HONG Y. Analysis and suggestion on comprehensive utilization of flue gas desulfurization gypsum in China. China Resources Comprehensive Utilization, 2013, 9: 42-43. (in Chinese)

[23] 陈欢, 王淑娟, 陈昌和, 徐旭常, 李跃进, 乌力更, 张伟华. 烟气脱硫废弃物在碱化土壤改良中的应用及效果. 干旱地区农业研究, 2005, 23(4): 38-42.

CHEN H, WANG S J, CHEN C H, XU X C, LI Y J, WU L G, ZHANG W H. The application and effect of desulphurized waste of flue gas in improving alkali soil. Agricultural Research in the Arid Areas, 2005, 23(4): 38-42. (in Chinese)

[24] 张姜涛, 景杰, 郭志宇, 宋宗理. 火电厂脱硫石膏的综合利用. 中国资源综合利用, 2014, 11: 38-40.

ZHANG J T, JING J, GUO Z Y, SONG Z L. Comprehensive utilization of flue gas desulfurization gypsum in thermal power plants. China Resources Comprehensive Utilization, 2014, 11: 38-40. (in Chinese)

[25] 耿春女, 钱华, 李小平, 罗启仕, 戴海夏, 程曦. 脱硫石膏农业利用研究进展与展望. 环境污染治理技术与设备, 2006, 7(12): 15-19.

GENG C N, QIAN H, LI X P, LUO Q S, DAI H X, CHENG X. Application of gypsums from flue gas desulfurization in agriculture. Techniques and Equipment for Environmental Pollution Control, 2006, 7(12): 15-19. (in Chinese)

[26] 王凯, 张庆国, 田富中. 湿法脱硫石膏特性研究进展. 环境工程, 2016, 34(增刊): 448-451.

WANG K, ZHANG Q G, TIAN F Z. Research progress on characteristics of wet desulfurization gypsum. Environmental Engineering, 2016, 34(suppl.): 448-451. (in Chinese)

[27] 万勤, 孟优, 陈平, 李杰. 石河子燃煤电厂重金属排放研究. 中国环境监测, 2015, 31(6): 130-133.

WAN Q, MENG Y, CHEN P, LI J. Emissions of heavy metals for coal-burning power plant in the Shihezi. Environmental Monitoring in China, 2015, 31(6): 130-133. (in Chinese)

[28] ALVAREZ-AYUSO E, QUEROL X, TOMA S A. Environmental impact of a coal combustion-desulphurisation plant: Abatement capacity of desulphurisation process and environmental characterisation of combustion by-products. Chemosphere, 2006, 65: 2009-2017.

[29] 徐胜光, 蓝佩玲, 廖新荣, 陈昌和, 徐旭常, 李淑仪. 燃煤烟气脱硫副产物的重金属环境行为. 生态环境, 2005, 14(1): 38-42.

XU S G, LAN P L, LIAO X R, CHEN C H, XU X C, LI S Y. Study on the environmental behaviors of heavy metals in desulphurization byproduct. Ecology and Environment, 2005, 14(1): 38-42. (in Chinese)

[30] 蓝佩玲, 廖新荣, 李淑仪, 王荣萍, 林刚, 陈昌和, 徐旭常. 燃煤烟气脱硫副产物在酸性土上的农用价值与利用原理. 生态环境, 2007, 16(4): 1135-1138.

LAN P L, LIAO X R, LI S Y, WANG R P, LIN G, CHEN C H, XU X C. The value and principle of the application of desulphurization byproducts to acidic soils in agriculture. Ecology and Environment, 2007, 16(4): 1135-1138. (in Chinese)

[31] 白向飞, 李文华, 陈亚飞, 姜英. 中国煤中微量元素分布基本特征. 煤质技术, 2007(1): 1-4.

BAI X F, LI W H, CHEN Y F, JIANG Y. The general distributions of trace elements in Chinese coals. Coal Quality Technology, 2007(1): 1-4. (in Chinese)

[32] 魏复盛, 陈静生, 吴燕玉, 郑春江. 中国土壤环境背景值研究. 环境科学, 1991, 12(4): 12-19.

WEI F S, CHEN J S, WU Y Y, ZHENG C J. Research on China's soil environmental background value. Environmental Science, 1991, 12(4): 12-19. (in Chinese)

[33] 李彦, 张峰举, 王淑娟, 罗成科, 赵博, 禚玉群, 陈昌和. 脱硫石膏改良碱化土壤对土壤重金属环境的影响. 中国农业科技导报, 2010, 12(6): 86-89.

LI Y, ZHANG F J, WANG S J, LUO C K, ZHAO B, ZHUO Y Q, CHEN C H. Environmental impact on alkali soil amelioration using FGD Gypsum. Journal of Agricultural Science and Technology, 2010, 12(6): 86-89. (in Chinese)

[34] 李丽君, 张强, 刘平, 白光洁, 武文丽. 火电厂烟气脱硫石膏重金属含量监测与分析. 水土保持学报, 2015, 29(2): 209-214.

LI L J, ZHANG Q, LIU P, BAI G J, WU W L. Survey and analysis of heavy metals in FGD gypsum from coal-fired power plants. Journal of Soil and Water Conservation, 2015, 29(2): 209-214. (in Chinese)

[35] 冯前伟, 张杨, 朱跃, 刘豪. 微波消解-ICP-MS测定脱硫石膏中的痕量元素. 粉煤灰综合利用, 2015(6): 39-42.

FENG Q W, ZHANG Y, ZHU Y, LIU H. Analysis of trace elements in desulfurization residues by microwave digestion and ICP-MS. Fly Ash Comprehensive Utilization, 2015(6): 39-42. (in Chinese)

[36] TANG Q, LIU GJ, YAN ZC, SUN RY. Distribution and fate of environmentally sensitive elements (arsenic, mercury, stibium and selenium) in coal-fired power plants at Huainan, Anhui, China. Fuel, 2012, 95: 334-339.

[37] 张峰举, 肖国举, 罗成科, 秦萍, 李彦. 脱硫石膏对次生碱化盐土的改良效果. 河南农业科学, 2010(2): 49-53.

ZHANG F J, XIAO G J, LUO C K, QIN P, LI Y. Reclamation of secondary alkaline saline soil with the flue gas desulfurization gypsum (FGDG). Henan Agricultural Science, 2010(2): 49-53. (in Chinese)

[38] WANG S J, CHEN Q, LI Y, ZHUO Y Q, XU L Z. Research on saline-alkali soil amelioration with FGD gypsum. Resources, Conservation and Recycling, 2017, 121: 82-92.

[39] ZHANG Y S, SHANG P F, WANG J W, NORRIS P, ROMERO C E, PAN W P. Trace element (Hg, As, Cr, Cd, Pb) distribution and speciation in coal-fired power plants. Fuel, 2017, 208: 647-654.

[40] 朱林. 江苏省燃煤电厂脱硫石膏资源综合利用方案研究[D]. 北京: 华北电力大学, 2014.

ZHU L. Research on resources comprehensive utilization of desulfurization gypsum in coal-fired power plant of Jiangsu Province[D]. Beijing: North China Electric Power University, 2014. (in Chinese)

[41] 樊文辉, 谭文轶, 张子昕, 朱昀焜, 吴帅妮. FGD石膏-胺(氨)系统对二氧化碳固定吸收重金属的影响. 第五届亚洲粉煤灰及脱硫石膏处理与利用技术国际交流大会. 中国朔州: 2017, 212-218.

FAN W H, TAN W Y, ZHANG Z X, ZHU Y K, WU S N. The influence of FGD gypsum-ammonia system on carbon dioxide fixation and absorption of heavy metals. The Fifth Asian Exchange Conference for Treatment and Utilization of Coal Ash and Desulphurization Gypsum. Shuozou, China: 2017, 212-218.

[42] HAO Y, LI Q, PAN Y, LIU Z X, WU S M, Xu Y B, Qian G R. Heavy metals distribution characteristics of FGD gypsum samples from Shanxi province 12 coal-fired power plants and its potential environmental impacts. Fuel, 2017, 209: 238-245.

[43] 曹晴, 邓双, 王相凤, 张凡, 张辰. 燃煤电厂固体副产物中汞含量测定及对环境影响研究//中国环境科学学会学术年会论文集. 北京: 中国环境科学学会, 2012: 2131-2135.

CAO J, DENG S, WANG X F, ZHANG F, ZHANG C. Determination on mercury contents in the solid by-products from coal-fired power plants and their environmental impacts//Proceedings of China Environmental Science Society Conference. Beijing: China Environmental Science Society, 2012: 2131-2135. (in Chinese)

[44] HAO Y, WU S M, PAN Y, LI Q, ZHOU J Z, XU Y B, QIAN G R. Characterization and leaching toxicities of mercury in flue gas desulfurization gypsum from coal-fired power plants in China. Fuel, 2016, 177: 157-163.

[45] 姚粉霞, 陈贵屏, 胡伟, 徐冰, 陈亚军, 封克. 利用不同有机和无机固体废物配制人工土壤的研究. 环境污染与防治, 2016, 38(1): 8-13.

YAO F X, CHEN G P, HU W, XU B, CHEN Y J, FENG K. Exploration of the artificial soil made of different organic and inorganic solid wastes. Environmental Pollution and Control, 2016, 38(1): 8-13. (in Chinese)

[46] 俄胜哲, 袁洁, 姚嘉斌, 海龙, 黄涛, 车宗贤, 袁金华, 王婷. 酒钢集团脱硫石膏养分及重金属含量特征研究. 中国农学通报, 2014, 30(33): 193-196.

E S Z, YUAN J, YAO J B, HAI L, HUANG T, CHE Z X, YUAN J H, WANG T. The study of nutrients and heavy metals content characteristics in desulfurized gypsum of Jiuquan Steel Group. Chinese Agricultural Science Bulletin, 2014, 30(33): 193-196. (in Chinese)

[47] 金婷, 朱廷钰, 叶猛, 匡俊艳, 荆鹏飞. 循环流化床烧结烟气脱硫灰理化性能研究. 北京化工大学学报(自然科学版), 2010, 37(6): 35-40.

JIN T, ZHU T Y, YE M, KUANG J Y, JING P F. Physical and chemical properties of circulating fluidized bed sintering flue gas desulfurization ash. Journal of Beijing University of Chemical Technology (Natural Science), 2010, 37(6): 35-40. (in Chinese)

[48] 邓双, 刘宇, 张辰, 王相凤, 曹晴, 王红梅, 张凡. 基于实测的燃煤电厂氟排放特征. 环境科学研究, 2014, 27(3): 225-231.

DENG S, LIU Y, ZHANG C, WANG X F, CAO Q, WANG H M, ZHANG F. Fluorine emission of pulverized coal-fired power plants in China. Research of Environmental Sciences, 2014, 27(3): 225-231. (in Chinese)

[49] 钟俊. 华北电力大学湿法烟气脱硫系统的脱汞性能及其副产品的汞释放特性[D]. 北京: 华北电力大学, 2014.

ZHONG J. Mercury removal performance of wet flue gas desulfurization system and mercury release characteristics of its by-products[D]. Beijing: North China Electric Power University. 2014. (in Chinese)

[50] 邓双, 张辰, 刘宇, 曹晴, 许月阳, 王宏亮, 张凡. 基于实测的燃煤电厂氯排放特征. 环境科学研究, 2014, 27(2): 127-133．

DENG S, ZHANG C, LIU Y, CAO Q, XU Y Y, WANG H L, ZHANG F. A full-scale field study on chlorine emission of pulverized coal-fired power plants in China. Research of Environmental Sciences, 2014, 27(2): 127-133. (in Chinese)

[51] 王宏霞, 张文生, 欧阳世翕. 烟气脱硫石膏中微量可溶性杂质的存在形态分析. 材料导报B, 2012, 26(12): 112-114.

WANG H X, ZHANG W S, OUYANG S X. Study on the configuration of soluble impurities in flue gas desulfurization gypsum. Material Review B, 2012, 26(12): 112-114. (in Chinese)

[52] 王兰英, 朱伟中, 窦正平, 吴潮, 袁洁, 黎昌昌. 脱硫石膏在内墙抹灰石膏中的资源综合利用. 砖瓦, 2017(1): 28-29.

WANG L Y, ZHU W Z, DOU Z P, WU C, YUAN J, LI C C. Comprehensive utilization of desulphurization gypsum producing internal wall plastering gypsum. Block-Brick-Tile, 2017(1): 28-29. (in Chinese)

[53] 李永亭. 烟气CFB干法脱硫与湿法脱硫的比较及应用前景. 发电设备, 2009(1): 65-68.

LI Y T. Comparison between dry CFB and wet flue gas desulfurization and the application prospects. Power Equipment, 2009(1): 65-68. (in Chinese)

[54] 张晓逵. 山西、河南部分煤中重金属元素的含量及其赋存形态研究[D]. 焦作: 河南理工大学, 2010.

ZHANG X K. The content of trace metals in coals from Shanxi, Henan province and their mode of occurrences[D]. Jiaozuo: Henan Polytechnic University, 2010. (in Chinese)

[55] 林珊珊, 蒋业兵, 苏清发, 吴慕正, 林驰前. 火电厂煤粉炉和钢铁厂烧结机干法脱硫副产物中重金属的分布和浸出特征. 安全与坏境学报, 2015, 15(6): 195-201.

LIN S S, JIANG Y B, SU Q F, WU M Z, LIN C Q. Heavy metal distribution and leaching characteristics of the dry flue gas desulfurization by products in pulverized coal combustion power plants and iron-steel sintering plant. Journal of Safety and Environment, 2015, 15(6): 195-201. (in Chinese)

[56] 曾少雁, 罗海中. 300MW级燃煤机组干法和湿法烟气脱硫工艺比较. 现代经济信息, 2009, 23: 298-300.

ZENG S Y, LUO H Z. Comparison between dry and wet flue gas desulfurization technology in a 300 MW coal-fired units. Modern Economic Information, 2009, 23: 298-300. (in Chinese)

[57] 韩立鹏. 火电厂干法脱硫灰再利用的研究. 电力科技与环保, 2012, 28(5): 38-39.

HAN L P. Study on comprehensive utilization of Circulation Fluidized Bed flue gas desulfurization residues. Electric Power Technology and Environmental Protection, 2012, 28(5): 38-39. (in Chinese)

[58] 陈捷, 李瑛, 赖立践, 张恒, 颜小禹. 燃煤锅炉烟气脱硫中脱硫剂的发展现状与展望. 工业加热, 2015, 44(6): 34-37.

CHEN J, LI Y, LAI L J, ZHANG H, YAN X Y. Current situation and its development of desulfurizer for flue gas desulfurization in the coal-fired boiler. Industrial Heating, 2015, 44(6): 34-37. (in Chinese)

[59] 中华人民共和国国家环境保护部和国家质量监督检验检疫总局. 固体废物鉴别标准通则: GB 34330—2017. 北京: 中国环境科学出版社, 2017.

State Environmental Protection Administration of the People's Republic of China and General Administration of Quality Supervision, Inspection and Quarantine of the People’s Republic of China. Identification Standards for Solid Wastes General Rules: GB 34330— 2017. Beijing: China Environmental Science Press, 2017. (in Chinese)

[60] 中华人民共和国国家环境保护总局和国家质量监督检验检疫总局. 土壤环境质量标准: GB 15618—1995. 北京: 中国环境科学出版社, 1995.

State Environmental Protection Administration of the People's Republic of China. Environmental Quality Standards for Soils: GB 15618—1995. Beijing: China Environmental Science Press, 1995. (in Chinese)

[61] 张东威. 中国土壤中硒及其土壤环境质量标准研究(简报). 水土保持研究, 1994(S1): 112.

ZHANG D W. The environmental quality standards of selenium in soils of China. Research of Soil and Water Conservation, 1994(S1): 112. (in Chinese)

[62] 李静, 谢正苗, 徐建明, 吴卫红. 中国氟的土壤健康质量指标及评价方法的初步探讨. 浙江大学学报(农业与生命科学版), 2005, 31(5): 593-597.

LI J, XIE Z M, XU J M, WU W H. Preliminary study on guideline on soil health quality index of fluorine and method of its evaluation in China. Journal of Zhejiang University (Agriculture and Life Science), 2005, 31(5): 593-597. (in Chinese)

[63] 王德清, 郭鹏程, 董翔云. 氯对作物毒害作用的研究. 土壤通报, 1990(6): 258-261.

WANGＤQ, GUO P C, DONG X Y. Study on the toxicity of chlorine to crops. Chinese Journal of Soil Science, 1990(6): 258-261. (in Chinese)

[64] 中华人民共和国国家环境保护总局和国家质量监督检验检疫总局. 危险废物鉴别标准浸出毒性鉴别: GB 5085.3—2007. 北京: 中国环境科学出版社, 2007.

State Environmental Protection Administration of the People's Republic of China and General Administration of Quality Supervision, Inspection and Quarantine of the People’s Republic of China. Identification Standards for Hazardous Wastes Identification for Extraction Toxicity: GB 5085.3—2007. Beijing: China Environmental Science Press, 2007. (in Chinese)

[65] 中华人民共和国国家环境保护局. 污水综合排放标准: GB 8978—1996. 北京: 中国标准出版社, 1996.

State Environmental Protection Administration of the People's Republic of China. Integrated Wastewater Discharge Standards: GB 8978—1996. Beijing: China Standard Press, 1996. (in Chinese)

[66] 中华人民共和国国家国家技术监督局. 地下水质量标准: GB/T 14848—93. 北京: 中国标准出版社, 1993.

General Administration of Quality Supervision, Inspection and Quarantine of the People’s Republic of China. Quality Standards for Ground Water: GB/T 1484—93. Beijing: China Standard Press, 1993. (in Chinese)

[67] 中华人民共和国国家环境保护总局和国家质量监督检验检疫总局. 一般工业固体废物贮存、处置场污染控制标准: GB 18599—2001. 北京: 中国环境科学出版社, 2001.

State Environmental Protection Administration of the People's Republic of China and General Administration of Quality Supervision, Inspection and Quarantine of the People’s Republic of China. Standard for Pollution Control on the Storage and Disposal Site For General Industrial Solid Wastes: GB 18599—2001. Beijing: China Environmental Science Press, 2001. (in Chinese)

[68] 王金满, 杨培岭, 张建国, 石懿. 脱硫石膏改良碱化土壤过程中的向日葵苗期盐响应研究. 农业工程学报, 2005, 21(9): 33-37.

WANG J M, YANG P L, ZHANG J G, SHI Y. Salinity effect on sunflower at seedling stage during improving sodic soils reclaimed with by-product from flue gas desulphurization (BFGD). Transactions of the Chinese Society of Agricultural Engineering, 2005, 21(9): 33-37.

(in Chinese)

[69] 王彬, 肖国举, 毛桂莲, 岳自慧, 许兴. 燃煤烟气脱硫废弃物对盐碱土的改良效应及对向日葵生长的影响. 植物生态学报, 2010, 34(10): 1227-1235.

WANG B, XIAO G J, MAO G L, YUE Z H, XU X. Effects of coal-fired flue gas desulfurated waste residue application on saline-alkali soil amelioration and oil-sunflower growth. Chinese Journal of Plant Ecology, 2010, 34(10): 1227-1235. (in Chinese)

[70] 王绍静, 吴晓琴, 刘成, 许勇, 余智. 柱淋滤模式下脱硫石膏中重金属组分的迁移特性. 环境工程学报, 2017, 11(4): 2512-2521.

WANG S J，WU X Q，LIU C，XU Y，YU Z. Research into mobility of heavy metals components in FGD gypsum on the basis of column leaching model. Chinese Journal of Environmental Engineering, 2017, 11(4): 2512-2521. (in Chinese)

[71] BALIGAR V C, CLARK R B, KORCAK R F, WRIGHT R J. Flue gas desulfurization product use on agricultural land. Advances in Agronomy, 2011, 111, 51-86.

Metrics

Viewed

Full text

Abstract

Cited

Shared

Discussed

Comments

Recommended 0

No Suggested Reading articles found!

Environment Risk for Application of Flue Gas Desulfurization Gypsum in Soils in China

RichHTML

PDF

Abstract

Cite this article

share this article

References

Related Articles 2

Metrics

Comments

Recommended 0

[1]	WANG XiaoBin, YAN Xiang, LI XiuYing. Environmental Safety Risk for Application of Anaerobic Fermentation Biogas Slurry from Livestock Manure in Agricultural Land in China [J]. Scientia Agricultura Sinica, 2021, 54(1): 110-139.
[2]	WANG XiaoBin,YAN Xiang,LI XiuYing,JI HongJie. Environmental Risks for Application of Phosphogysum in Agricultural Soils in China [J]. Scientia Agricultura Sinica, 2019, 52(2): 293-311.