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中国农业科学 ›› 2019, Vol. 52 ›› Issue (21): 3852-3865.doi: 10.3864/j.issn.0578-1752.2019.21.014

• 专题:土壤磷素演变与高效利用 • 上一篇    下一篇

等有机质 土有效磷和无机磷形态的关系

李若楠,王政培,BATBAYARJavkhlan,张东杰,张树兰,杨学云()   

  1. 西北农林科技大学资源环境学院/农业农村部西北植物营养与农业环境重点实验室,陕西杨凌 712100
  • 收稿日期:2019-06-06 接受日期:2019-09-23 出版日期:2019-11-01 发布日期:2019-11-12
  • 通讯作者: 杨学云
  • 作者简介:李若楠,E-mail: liruonan0104@163.com
  • 基金资助:
    国家重点研发计划项目(2017YFD0200205)

Relationship Between Soil Available Phosphorus and Inorganic Phosphorus Forms Under Equivalent Organic Matter Condition in a Tier Soil

LI RuoNan,WANG ZhengPei,BATBAYAR Javkhlan,ZHANG DongJie,ZHANG ShuLan,YANG XueYun()   

  1. College of Natural Resources and Environment, Northwest A&F University/Key Laboratory of Plant Nutrition and the Agro-environment in Northwest China, Ministry of Agriculture and Rural Affairs, Yangling 712100, Shaanxi
  • Received:2019-06-06 Accepted:2019-09-23 Online:2019-11-01 Published:2019-11-12
  • Contact: XueYun YANG

摘要:

目的 在有机质含量相同的土壤上探讨土壤无机磷组分对有效磷的贡献,为合理的磷肥管理提供决策依据。方法 采集并筛选陕西关中平原冬小麦-夏玉米种植区 土有机质含量相近(10.03-10.68 g·kg -1),有效磷含量梯度(平均分别为10.73、18.06、20.61、24.01、30.73、43.69和58.58 mg·kg -1)的土壤样品,采用蒋柏藩-顾益初改进的Chang和Jackson无机磷分级方法进行磷组分测定。 结果 西北冬小麦-夏玉米种植区耕层土壤的无机磷以钙磷为主,约占无机磷总量的66.67%,其中磷酸二钙(Ca2-P),磷酸八钙(Ca8-P)和磷灰石(Ca10-P)分别占2.80%、16.80%和47.09%;铝结合的磷酸盐(Al-P),铁结合的磷酸盐(Fe-P)和闭蓄态磷酸盐(O-P)分别占16.28%、5.23%和11.81%。随着Ca2-P、Ca8-P、Ca10-P、Al-P、Fe-P和O-P含量的增加,Olsen P呈显著线性增加;磷活化系数(土壤有效磷与全磷之比,PAC)与Ca2-P、Ca8-P、Al-P、Fe-P和O-P呈显著线性正相关关系。通径分析结果表明,该区域土壤无机磷对土壤有效磷(Olsen P)的贡献依次为Ca2-P(0.974)>Al-P(0.186)>Ca8-P(0.182)>Fe-P(0.150)>Ca10-P(0.007)>O-P(-0.074),各形态无机磷对磷活化系数(PAC)的贡献为:Ca2-P(0.768)>Al-P(0.082)>Ca8-P(0.071)>Fe-P(-0.018)>Ca10-P(-0.055)>O-P(-0.388),与土壤磷组分对有效磷的贡献大体一致。逐步回归分析结果表明,Ca2-P和Ca8-P对Olsen P贡献最大,但仅Ca2-P对PAC的贡献最大。结论 在有机质相同或相近条件下,Ca2-P是陕西关中平原小麦-玉米种植区 土最有效的磷源。土壤磷有效性的提高主要通过增加高有效性的磷形态比(例如Ca2-P)和缓效磷形态(如Ca8-P、Al-P),降低土壤中有效性极低的Ca10-P的比例来实现的。由此看来,关中平原长期施用磷肥土壤磷仍主要以有效性相对较高的磷素形态存在。

关键词: 无机磷形态, 冬小麦-夏玉米体系, 14李若楠(校样), 土')">土, 磷有效性, 有效磷梯度

Abstract:

【Objective】 Investigating the contribution of inorganic phosphorus (P) fractions to soil available phosphorus under equivalent soil organic matter content might be helpful in development of phosphate fertilizer management strategy whereby to improve phosphorus use efficiency in a given soil.【Method】 We collected and screened the soils with a gradient of Olsen P level but the quite similar soil organic matter content (SOC ranges from 10.03 to 10.68 g·kg -1) in a Tier soil under winter wheat-summer maize cropping in Guanzhong Plain of Shaanxi Province. The Olsen P contents of the selected soil samples were 10.73 mg·kg -1, 18.06 mg·kg -1, 20.61 mg·kg -1, 24.01 mg·kg -1, 30.73 mg·kg -1, 43.69 mg·kg -1, and 58.58 mg·kg -1, respectively. We then analyzed the soil inorganic phosphorus forms with the phosphorus fractionation method developed by Chang & Jackson and modified by Jiang & Gu.【Result】 The results showed that the calcium bounded phosphorus fraction was the dominant form in the cultivated soil in the northwestern winter wheat-summer maize planting area, accounting for 66.67% of the total amount of inorganic phosphorus, of which dicalcium phosphate (Ca2-P), octa-calcium phosphate (Ca8-P) and apatite (Ca10-P) account for 2.80%, 16.80% and 47.09%, respectively, on average; and aluminum bounded phosphate (Al-P), iron bounded phosphate (Fe-P) and occluded phosphate (O-P) composed of 16.28%, 5.23% and 11.81%, respectively. Soil Olsen P was increased significantly and linearly with the increasing content of Ca2-P, Ca8-P, Ca10-P, Al-P, Fe-P and O-P; while the phosphorus activation coefficients, defined as the ratio of soil Olsen P to total P, were correlated significantly positively and linearly to the content of Ca2-P, Ca8-P, Al-P, Fe-P and O-P. The results of path analysis showed that the contribution of inorganic phosphorus to soil available phosphorus (Olsen P) in Guanzhong Plain area of Shaanxi Province was in the order of Ca2-P (0.974)>Al-P (0.186)>Ca8-P (0.182)>Fe-P (0.150)>Ca10-P (0.007)>O-P (-0.074), the contribution of inorganic phosphorus to phosphorus activation coefficient (PAC) was Ca2-P (0.768)>Al-P (0.082)>Ca8-P (0.071)>Fe-P (-0.018)>Ca10-P (-0.055)>O-P (-0.388), which was consistent with the contribution of soil phosphorus component to available phosphorus. The results of stepwise regression analysis showed that Ca2-P and Ca8-P were the major two contributors to Olsen P, but the Ca2-P contributed the most to PAC.【Conclusion】 Under the same or similar soil organic matter condition, Ca2-P was the most effective phosphorus source in Tier soil of wheat-maize growing area in Guanzhong Plain of Shaanxi Province. The increase of soil phosphorus availability was mainly achieved by increasing the proportion of phosphorus forms of readily available and relatively high availability such as Ca2-P, Ca8-P and Al-P, and reducing the proportion of very low availability forms, i.e. Ca10-P. Generally, under current cropping system, the application of phosphate fertilizers mainly kept the soil phosphorus in pools of available forms in the Guanzhong Plain.

Key words: forms of inorganic phosphorus, winter wheat summer maize cropping, tier, phosphorus availability, Olsen P gradient