多功能金属有机框架材料赋能绿色农业：应用与展望

doi:10.1016/j.jia.2026.01.007

摘要/Abstract

摘要：

现代农业正面临前所未有的挑战：全球人口增长、耕地资源有限、淡水资源匮乏以及农用化学品低效使用已引发严重的环境退化。农药、重金属、微塑料、抗生素、养分径流和温室气体等污染物正威胁生态系统稳定性、粮食安全及人类健康。金属有机框架材料凭借其可调控结构、高孔隙率和多功能性，成为解决这些问题的潜力材料。本文全面综述了基于MOF的农业解决方案的最新进展，涵盖提升结构稳定性并遵循循环经济原则的绿色合成策略。其应用主要涉及三大领域：污染物修复、可持续技术（如大气水收集、海水淡化和绿氨合成）以及智慧农业系统。后者能够实现农用化学品的可控释放与实时传感监测。最后，本文探讨了当前面临的挑战（包括成本、生物安全和规模化），并展望了人工智能辅助设计、可回收性提升、规模化生产及面向绿色智慧农业的多功能集成等前瞻性研究方向。

Abstract:

Modern agriculture faces unprecedented challenges: A growing global population, limited arable land, freshwater scarcity, and inefficient agrochemical use have triggered severe environmental degradation. Pollutants including pesticides, heavy metals, microplastics, antibiotics, nutrient runoff, and greenhouse gases threaten ecosystem stability, food security, and human health. Metal-organic frameworks (MOFs), with their tunable structures, high porosity, and versatile functionality, emerge as promising materials to address these issues. This review comprehensively summarizes recent advances in MOFs-based solutions for agriculture. It covers green synthesis strategies to enhance structural stability and promote circular economy principles. Applications span three primary domains: pollutant remediation, sustainable technologies (e.g., atmospheric water harvesting, seawater desalination, and green ammonia synthesis), and smart agricultural systems. The latter enables controlled agrochemical release and real-time sensing and monitoring. Finally, challenges - such as high costs, biosafety concerns, and scalability limitations - are discussed, alongside forward-looking perspectives including AI-assisted design, improved recyclability, scalable production, and multifunctional integration toward green and smart agriculture.

Key words: MOFs , pollutant remediation , green synthesis , sustainable technologies , smart agriculture

Lianjie Wan, Fei Ma, Jianmin Zhou, Changwen Du. 多功能金属有机框架材料赋能绿色农业：应用与展望[J]. Journal of Integrative Agriculture, 2026, 25(5): 1788-1812.

Lianjie Wan, Fei Ma, Jianmin Zhou, Changwen Du. Green agriculture enabled by versatile metal-organic frameworks: A review[J]. Journal of Integrative Agriculture, 2026, 25(5): 1788-1812.

参考文献

Abdollahi N, Moussavi G, Giannakis S. 2022. A review of heavy metals’ removal from aqueous matrices by metal-organic frameworks (MOFs): state-of-the art and recent advances. Journal of Environmental Chemical Engineering, 10, 107394.

Abuzalat O, Wong D, Elsayed M, Park S, Kim S. 2018. Sonochemical fabrication of Cu(II) and Zn(II) metal-organic framework films on metal substrates. Ultrasonics Sonochemistry, 45, 180–188.

Adusumalli V, Gupta A, Lee S Y, Park Y I. 2023. Ligand emission-based turn-on sensing of glyphosate via competitive coordination with NH2-MIL-88B (Fe) MOF nanocrystals. ACS Applied Nano Materials, 6, 21016–21026.

Ahmed B, Shabbir H, Naqvi S R, Peng L. 2024. Smart agriculture: current state, opportunities, and challenges. IEEE Access, 12, 144456–144478.

Akhter S, Bhat M A, Ahmed S, Siddiqui W A. 2024. Antibiotic residue contamination in the aquatic environment, sources and associated potential health risks. Environmental Geochemistry and Health, 46, 387.

Bhomick P C, Ivanovska E H, Mahmoud L A M, Doan H V, Terry L R, Addicoat M A, Rowlandson J L, Rochat S, Ting V P, Nayak S. 2025. Iron-based metal-organic frameworks and their polymer composites for sustainable delivery of herbicides. ACS Omega, 10, 9051–9061.

Carné-Sánchez A, Imaz I, Cano-Sarabia M, Maspoch D. 2013. A spray-drying strategy for synthesis of nanoscale metal-organic frameworks and their assembly into hollow superstructures. Nature Chemistry, 5, 203–211.

Chai L L, Pan J Q, Hu Y, Qian J J, Hong M C. 2021. Rational design and growth of MOF-on-MOF heterostructures. Small, 17, 2100607.

Chakraborty S, Dhumal P, Guo Z, Gifford M L, Lynch I. 2025. From soil to table: How safe and sustainable by design MOFs can revolutionize agriculture and food security. Matter, 8, 102095.

Chang M, Wang F, Liu Z, Yi X-H, Chu H, Zhang L, Zhao X, Wang C-C, Wang P, Wang J. 2025. Mining iron from stainless steel pickling wastewater to produce quasi-MIL-100(Fe) for boosted photocatalytic peroxymonosulfate activation. Nano Research, 18, 94907382.

Channab B E, El Idrissi A, Ammar A, Akil A, White J C, Zahouily M. 2024. ZIF-8 metal organic framework, carboxymethylcellulose and polyvinyl alcohol bio-nanocomposite controlled-release phosphorus fertilizer: improved P management and tomato growth. Chemical Engineering Journal, 495, 153610.

Chen E Y, Jia L J, Chen C, Huang F, Zhang L. 2021. Understanding the transport mechanism of seawater through FMOF-1 and its derivative via molecular dynamics simulation. Journal of Molecular Liquids, 325, 115209.

Chen H, Yuan X, Jiang L, Wang H, Zeng G. 2022. Highly efficient As(III) removal through simultaneous oxidation and adsorption by N-CQDs modified MIL-53(Fe). Separation and Purification Technology, 286, 120409.

Chen H Y, You Z H, Wang X, Qiu Q M, Ying Y B, Wang Y X. 2022. An artificial olfactory sensor based on flexible metal-organic frameworks for sensing VOCs. Chemical Engineering Journal, 446, 137098.

Chen M L, Guo Y C, Yang F, Liang J X, Cao Z X, Zhou Z H. 2014. A lanthanum chelate possessing an open-channel framework with water nanotubes: properties and desalination. Dalton Transactions, 43, 6026–6031.

Chen Y J, Chen Y F, Miao C, Wang Y R, Gao G K, Yang R X, Zhu H J, Wang J H, Li S L, Lan Y Q. 2020. Metal-organic framework-based foams for efficient microplastics removal. Journal of Materials Chemistry A, 8, 14644–14652.

Chen Y W, Wu H X, Liu Z W, Sun X J, Xia Q B, Li Z. 2018. Liquid-assisted mechanochemical synthesis of copper based MOF-505 for the separation of CO2 over CH4 or N2. Industrial & Engineering Chemistry Research, 57, 703–709.

Chinglenthoiba C, Mahadevan G, Zuo J W, Prathyumnan T, Valiyaveettil S. 2024. Conversion of PET bottle waste into a terephthalic acid-based metal-organic framework for removing plastic nanoparticles from water. Nanomaterials, 14, 257.

Chu H Y, Liu Z X, Wang C C, Wang P. 2024. Sustainable production and applications of metal-organic frameworks. Chemical Communications, 60, 8350–8359.

Cui Z, Li Y, Tsyusko O V, Wang J, Unrine J M, Wei G, Chen C. 2024. Metal-organic framework-enabled sustainable agrotechnologies: an overview of fundamentals and agricultural applications. Journal of Agricultural and Food Chemistry, 72, 8890–8905.

Dapaah M F, Liu B J. 2020. Recent advances of supercritical CO2 in green synthesis and activation of metal-organic frameworks. Journal of Inorganic and Organometallic Polymers and Materials, 30, 581–595.

Deacon A, Briquet L, Malankowska M, Massingberd-Mundy F, Rudic S, Hyde T L, Cavaye H, Coronas J, Poulston S, Johnson T. 2022. Understanding the ZIF-L to ZIF-8 transformation from fundamentals to fully costed kilogram-scale production. Communications Chemistry, 5, 18.

Demir H, Daglar H, Gulbalkan H C, Aksu G O, Keskin S. 2023. Recent advances in computational modeling of MOFs: from molecular simulations to machine learning. Coordination Chemistry Reviews, 484, 215112.

Dong F D, Wang X, Zhao Z Q, Gao S, Wang G, Li K, Lin Y Q. 2023. Ligand “lock and fix”strategy provides stability to metal-organic frameworks for photodegradation processes. Cell Reports Physical Science, 4, 101545.

Dong Y, Hu T, Pudukudy M, Su H, Jiang L, Shan S, Jia Q. 2020. Influence of microwave-assisted synthesis on the structural and textural properties of mesoporous MIL-101(Fe) and NH2-MIL-101(Fe) for enhanced tetracycline adsorption. Materials Chemistry and Physics, 251, 123060.

Du M, Xu G, Zhang J, Li T, Guan Y, Guo C. 2022. Effect of H2O/DMF mixed solvents on formation of MIL-100(Fe) and dye adsorption. Journal of Solid State Chemistry, 312, 123248.

Du Y X, Xu X B, Ma F, Du C W. 2021. Solvent-free synthesis of iron-based metal-organic frameworks (MOFs) as slow-release fertilizers. Polymers, 13, 561.

Duan J J, Xin X, Guo S J, Wang S L, Chen H, Li J L, Qin S, Tao G H. 2023. Regulating defected zirconium metal-organic frameworks in ionic liquid for sewage treatment. Journal of Molecular Structure, 1286, 135607.

Eddaoudi M, Kim J, Rosi N, Vodak D, Wachter J, O’Keeffe M, Yaghi O M. 2002. Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage. Science, 295, 469–472.

Fang Y, Wen J, Zeng G, Jia F, Zhang S, Peng Z, Zhang H. 2018. Effect of mineralizing agents on the adsorption performance of metal-organic framework MIL-100(Fe) towards chromium(VI). Chemical Engineering Journal, 337, 532–540.

Feng L, Pang J D, She P, Li J L, Qin J S, Du D Y, Zhou H C. 2020. Metal-organic frameworks based on group 3 and 4 metals. Advanced Materials, 32, 2070327.

FitzGerald L I, Sutton A L, Seeber A J, Muir B W, Doherty C M. 2025. Solvent-free synthesis of fumarate-based metal-organic frameworks with resonant acoustic mixing. ACS Omega, 10, 19206–19213.

Furukawa H, Cordova K E, O’Keeffe M, Yaghi O M. 2013. The chemistry and applications of metal-organic frameworks. Science, 341, 1230444.

Gao D G, Ji H D, Li R L, Munir M T, Wu X F, Huang Y F, Li B. 2023. Advancing sustainable phosphorus removal and recovery with metal-organic frameworks (MOFs). Chemical Engineering Journal, 475, 145949.

Gao Y, Liang Y, Zhou Z, Yang J, Tian Y, Niu J, Tang G, Tang J, Chen X, Li Y, Cao Y. 2021. Metal-organic framework nanohybrid carrier for precise pesticide delivery and pest management. Chemical Engineering Journal, 422, 130143.

Gropp C, Canossa S, Wuttke S, Gándara F, Li Q, Gagliardi L, Yaghi O M. 2020. Standard practices of reticular chemistry. ACS Central Science, 6, 1255–1273.

Guan X, Dai Y, Li X, Han Z, Li X, Su Z, Wang X, Wang L, Xu M. 2025. Acetochlor promotes the aging of mulch-derived microplastics in soil by altering the plastisphere microbial community. Journal of Hazardous Materials, 494, 138641.

Guan X, Li Q, Maimaiti T, Lan S, Ouyang P, Ouyang B, Wu X, Yang S-T. 2021. Toxicity and photosynthetic inhibition of metal-organic framework MOF-199 to pea seedlings. Journal of Hazardous Materials, 409, 124521.

Guo L Z, Wang Y Q, Wang M, Shaghaleh H, Hamoud Y A, Xu X, Liu H. 2021. Synthesis of bio-based MIL-100(Fe)@CNF-SA composite hydrogel and its application in slow-release N-fertilizer. Journal of Cleaner Production, 324, 129274.

Guo Z Q, Zhou J, Hou H, Wu X M, Li Y. 2023. Recyclable Mg-MOF-74@cellulose aerogel composites for efficient removal of heavy metals from wastewater. Journal of Solid State Chemistry, 323, 124059.

Han L, Ma J, Lin H J, Chen C, Teng J H, Li B S, Zhao D L, Xu Y C, Yu W, Shen L G. 2023. A novel flower-like nickel-metal-organic framework (Ni-MOF) membrane for efficient multi-component pollutants removal by gravity. Chemical Engineering Journal, 470, 144311.

Han L Z, Qin P G, Li M Y, Li D, Mu M Y, Gao Y M, Zhu S P, Lu M H, Cai Z W. 2023. Hierarchically porous zirconium-based metal-organic frameworks for rapid adsorption and enrichment of sulfonamide antibiotics. Chemical Engineering Journal, 456, 140969.

Han Y, Ji C, Lou Y, Li R, He M, Yuan D, Han Z. 2025. Topology-directed cage engineering in MOFs for efficient C2H2/CO2/C2H4 separation. Journal of the American Chemical Society, 147, 19262–19271.

He B, Sadiq M M, Batten M P, Suzuki K, Rubio-Martinez M, Gardiner J, Hill M R. 2019. Continuous flow synthesis of a Zr magnetic framework composite for post-combustion CO2 capture. Chemistry (A: European Journal), 25, 13184–13188.

He L, Wang Z, Wang H, Wu Y N. 2025. Are MOFs ready for environmental applications: assessing stability against natural stressors? Coordination Chemistry Reviews, 526, 216361.

He P, Hu Z, Dai Z, Bai H, Fan Z, Niu R, Gong J, Zhao Q, Tang T. 2023. Mechanochemistry milling of waste poly(ethylene terephthalate) into metal-organic frameworks. ChemSusChem, 16, e202201935.

Hillman F, Brito J, Jeong H K. 2018. Rapid one-pot microwave synthesis of mixed-linker hybrid zeolitic-imidazolate framework membranes for tunable gas separations. ACS Applied Materials & Interfaces, 10, 5586–5593.

Hou D, Jia X, Wang L, McGrath S P, Zhu Y-G, Hu Q, Zhao F-J, Bank M S, O’Connor D, Nriagu J. 2025. Global soil pollution by toxic metals threatens agriculture and human health. Science, 388, 316–321.

Hou Y S, Zhang Y W, Huang Y Y, Zhou A L, Han J T, Yang K X, Zhao Y M, Zhou J, Wang J, Chen G, Xu X M, Xu D H, Lv J, Chen J, Lv H H, Liu G Y. 2024. A pH-responsive MOFs@MPN nanocarrier with enhancing antifungal activity for sustainable controlling myclobutanil release. Chemical Engineering Journal, 497, 155713.

Hu Y, Wang Y, Fang Z, Yao B, Ye Z, Peng X. 2023. Ca-MOF-derived porous sorbents for high-yield solar-driven atmosphere water harvesting. ACS Applied Materials & Interfaces, 15, 44942–44952.

Huang B W, Wang R J, Hu W B, Xu H, Chen Q, Liu T S, Fan Y M, Kong Y. 2025. Preparation and performance of MOF-808 (Zr-MOF) for the efficient adsorption of phenoxyacetic acid pesticides. Journal of Industrial and Engineering Chemistry, 143, 293–302.

Huang Z, Wang Z Z, Rabl H, Naghdi S, Zhou Q C, Schwarz S, Apaydin D H, Yu Y, Eder D. 2024. Ligand engineering enhances (photo) electrocatalytic activity and stability of zeolitic imidazolate frameworks via in-situ surface reconstruction. Nature Communications, 15, 9393.

Hyun T, Park J, So J, Kim J, Koh D Y. 2024. Unexpected molecular sieving of xylene isomer using tethered ligand in polymer-metal-organic frameworks (polyMOFs). Advanced Science, 11, 2402980.

Ito T, Jenkins S G, Seifert S, Uysal A. 2023. Electrochemistry-induced direct deposition of nanoscale thin zeolitic imidazolate framework-8 films on insulator substrates. Crystal Growth & Design, 23, 6369–6377.

Jabarian S, Ghaffarinejad A. 2019. Electrochemical synthesis of nibtc metal organic framework thin layer on nickel foam: an efficient electrocatalyst for the hydrogen evolution reaction. Journal of Inorganic and Organometallic Polymers and Materials, 29, 1565–1574.

Jia W W, Fan R Q, Zhang J, Zhu K, Gai S, Yin Y Y, Yang Y L. 2022. Smart MOF-on-MOF hydrogel as a simple rod-shaped core for visual detection and effective removal of pesticides. Small, 18, 2201510.

Jiang K, Yang J, Zhou Y, Gu J. 2024. Synergetic enhancement of CO2 direct air capture with monoethanolamine-impregnated MIL-101(Cr) MOFs. Microporous and Mesoporous Materials, 366, 112920.

Jing Y, Gong F, Wang S, Wang W, Yang P, Fu E, Xiao R. 2024. Activating the synergistic effect in Ni-Co bimetallic MOF for enhanced plasma-assisted ammonia synthesis. Fuel, 368, 131686.

Jung B K, Hasan Z, Jhung S H. 2013. Adsorptive removal of 2,4-dichlorophenoxyacetic acid (2,4-D) from water with a metal-organic framework. Chemical Engineering Journal, 234, 99–105.

Jung D B, Song Y, Lee Y R, Cha M J, Jeong K, Choi J, Na J, Seo J Y, Baek K Y. 2025. Quaternarized chitosan nanofiber and ZIF aerogel composites for synergetic CO2 cycloaddition catalysis. Carbohydrate Polymers, 347, 122685.

Kalmutzki M J, Hanikel N, Yaghi O M. 2018. Secondary building units as the turning point in the development of the reticular chemistry of MOFs. Science Advances, 4, eaat9180.

Kang M S, Heo I, Park S H, Bae J, Kim S, Kim G, Kim B H, Jeong N C, Yoo W C. 2024. Time-efficient atmospheric water harvesting using fluorophenyl oligomer incorporated MOFs. Nature Communications, 15, 9793.

Karimi-Maleh H, Ghalkhani M, Dehkordi Z S, Tehran M M, Singh J, Wen Y P, Baghayeri M, Rouhi J, Fu L, Rajendran S. 2024. MOF-enabled pesticides as developing approach for sustainable agriculture and reducing environmental hazards. Journal of Industrial and Engineering Chemistry, 129, 105–123.

Kim H, Yang S, Rao S R, Narayanan S, Kapustin E A, Furukawa H, Umans A S, Yaghi O M, Wang E N. 2017. Water harvesting from air with metal-organic frameworks powered by natural sunlight. Science, 356, 430–432.

Kumar P, Anand B, Tsang Y F, Kim K-H, Khullar S, Wang B. 2019. Regeneration, degradation, and toxicity effect of MOFs: opportunities and challenges. Environmental Research, 176, 108488.

Lai Y W, He J, Li Y C, Zhou S L, Yan W T, Zhou Y, Gao C J. 2024. Preparation of hydrophilic modified ZIF-8 and its application in the preparation of nanocomposite matrix reverse osmosis membrane with improved permeation performance. Journal of Coatings Technology and Research, 21, 683–692.

Lan Y S, Yan O G, Tong M M, Zhong C L. 2019. Large-scale computational assembly of ionic liquid/MOF composites: synergistic effect in the wire-tube conformation for efficient CO2/CH4 separation. Journal of Materials Chemistry, 7, 12556–12564.

Lee G, Hossain M A, Yoon M, Jhung S H. 2023. Nanoarchitectonics of metal-organic frameworks having hydroxy group for adsorption, catalysis, and sensing. Journal of Industrial and Engineering Chemistry, 119, 181–192.

Li D, Yan X, Xing C C, Zhang P, Zhai Q G. 2024. Wide-range temperature sensing regulated by the excited-state intramolecular proton transfer in main-group metal-organic frameworks. Journal of Solid State Chemistry, 333, 124601.

Li H, Eddaoudi M, O’Keeffe M, Yaghi O M. 1999. Design and synthesis of an exceptionally stable and highly porous metal-organic framework. Nature, 402, 276–279.

Li H X, Lu Q, Shi J X, Zhang X G, Sun P, Yan X, Lu G Y. 2024. Enzyme-engineered metal-organic frameworks for the construction of organophosphorus pesticide biosensor. Advanced Functional Materials, 34, 2309383.

Li J, Wang W, Chen W, Gong Q, Luo J, Lin R, Xin H, Zhang H, Wang D, Peng Q, Zhu W, Chen C, Li Y. 2018. Sub-nm ruthenium cluster as an efficient and robust catalyst for decomposition and synthesis of ammonia: break the “size shackles”. Nano Research, 11, 4774–4785.

Li M, Li L, Wang S, Sun Y, Zhang H, Li F. 2025. Development of MOF exoskeleton with robust cytoprotection on bacterial cells enables enhanced bioremediation of pesticide pollution in soil. Pesticide Biochemistry and Physiology, 213, 106534.

Li N, Xu J, Feng R, Hu T L, Bu X H. 2016. Governing metal-organic frameworks towards high stability. Chemical Communications, 52, 8501–8513.

Li Q, Zhang Y, Guo X, Yang Z, Wang Y, Chen Y, Liu Y, Yue H, Gao S, Zhou H, Huang J, Shakouri M, Wang Y, Zhu G, Liu Z, Zhang Y, Pang H. 2025. Nucleation and growth mechanisms of micro/nano structural manganese-trimesic acid coordinations for aqueous zinc-ion batteries. Angewandte Chemie (International Edition), 64, e202509741.

Li Y, Li M, Shakoor N, Wang Q, Zhu G, Jiang Y, Wang Q, Azeem I, Sun Y, Zhao W, Gao L, Zhang P, Rui Y. 2024. Metal-organic frameworks for sustainable crop disease management: current applications, mechanistic insights, and future challenges. Journal of Agricultural and Food Chemistry, 72, 22985–23007.

Li Y, Zhou K, He M, Yao J F. 2016. Synthesis of ZIF-8 and ZIF-67 using mixed-base and their dye adsorption. Microporous and Mesoporous Materials, 234, 287–292.

Li Z J, Guo Z Y, Xie J W, Zhao G M, Liu Y. 2024. MOF-based photothermal Janus membrane with robust anti-fouling performance for enhanced membrane distillation. Desalination, 592, 118203.

Liang W, Cheng J, Zhang J, Xiong Q, Jin M, Zhao J. 2022. pH-responsive on-demand alkaloids release from core-shell ZnO@ZIF-8 nanosphere for synergistic control of bacterial wilt disease. ACS Nano, 16, 2762–2773.

Liang Y, Guo M C, Fan C, Dong H Q, Ding G L, Zhang W B, Tang G, Yang J L, Kong D D, Cao Y S. 2017. Development of novel urease-responsive pendimethalin microcapsules using silica-IPTS-PEI as controlled release carrier materials. ACS Sustainable Chemistry & Engineering, 5, 4802–4810.

Liao X, Wang F, Wang F, Cai Y, Yao Y, Teng B T, Hao Q, Shuxiang L. 2019. Synthesis of (100) surface oriented MIL-88A-Fe with rod-like structure and its enhanced fenton-like performance for phenol removal. Applied Catalysis (B: Environmental), 259, 118064.

Lin G, Zeng B, Li J, Wang Z Y, Wang S X, Hu T, Zhang L B. 2023. A systematic review of metal organic frameworks materials for heavy metal removal: synthesis, applications and mechanism. Chemical Engineering Journal, 460, 141710.

Lin X Y, Guo L Z, Shaghaleh H, Hamoud Y A, Xu X, Liu H. 2021. A TEMPO-oxidized cellulose nanofibers/MOFs hydrogel with temperature and pH responsiveness for fertilizers slow-release. International Journal of Biological Macromolecules, 191, 483–491.

Liu J C, Xu D J, Xu G C, Li X A, Dong J T, Luan X K, Du X Z. 2023. Smart controlled-release avermectin nanopesticides based on metal-organic frameworks with large pores for enhanced insecticidal efficacy. Chemical Engineering Journal, 475, 146312.

Liu P, Yan J, Huang H, Song W. 2023. Cu/Co bimetallic conductive MOFs: electronic modulation for enhanced nitrate reduction to ammonia. Chemical Engineering Journal, 466, 143134.

Liu S, Zhang Y, Meng Y, Gao F, Jiao S, Ke Y. 2013. Fast syntheses of MOFs using nanosized zeolite crystal seeds in situ generated from microsized zeolites. Crystal Growth & Design, 13, 2697–2702.

Liu S X, Teng Z Y, Liu H, Wang T Y, Wang G X, Xu Q, Zhang X Y, Jiang M, Wang C Y, Huang W, Pang H. 2022. A Ce-UiO-66 metal-organic framework-based graphene-embedded photocatalyst with controllable activation for solar ammonia fertilizer production. Angewandte Chemie (International Edition), 61, e202207026.

Loera-Serna S, Beltrán H I, Mendoza-Sánchez M, Álvarez-Zeferino J C, Almanza F, Fernández-Luqueño F. 2024. Effect of HKUST-1 metal-organic framework in root and shoot systems, as well as seed germination. Environmental Science and Pollution Research, 31, 13270–13283.

Luo F, Liao T, Liang X, Chen W, Wang S, Gao X, Zhang Z, Fang Y. 2022. Two-linker MOFs-based glass fiber paper monolithic adsorbent for atmospheric water harvesting in arid climates. Journal of Cleaner Production, 373, 133838.

Lv Y, Ke S W, Gu Y M, Tian B L, Tang L Y, Ran P, Zhao Y, Ma J, Zuo J L, Ding M N. 2023. Highly efficient electrochemical nitrate reduction to ammonia in strong acid conditions with Fe2M-trinuclear-cluster metal-organic frameworks. Angewandte Chemie (International Edition), 62, e202305246.

Ma Q, Xue Y H, Zhang C N, Chen Y Y, Teng W, Zhang H, Fan J W. 2025. 2D copper-iron bimetallic metal-organic frameworks for reduction of nitrate with boosted efficiency and ammonia selectivity. Journal of Environmental Sciences, 149, 374–385.

Ma S, Wang Y, Yang X, Ni B, Lü S. 2022. MOF hybrid for long-term pest management and micronutrient supply triggered with protease. ACS Applied Materials & Interfaces, 14, 17783–17793.

Menozzi C, Spoorenberg T, Bassarsky L. 2024. World population prospects 2024: summary of results. UN DESA, New York.

Millward A R, Yaghi O M. 2005. Metal-organic frameworks with exceptionally high capacity for storage of carbon dioxide at room temperature. Journal of the American Chemical Society, 127, 17998–17999.

Modak S, Kasula M, Esfahani M R. 2023. Nanoplastics removal from water using metal-organic framework: investigation of adsorption mechanisms, kinetics, and effective environmental parameters. ACS Applied Engineering Materials, 1, 744–755.

Modi A, Kasher R. 2024. Nitrate removal from contaminated groundwater by micellar-enhanced ultrafiltration using a polyacrylonitrile membrane with a hydrogel-stabilized ZIF-L layer. Water Research, 254, 121384.

Mohajer H, Toosi M R, Zardoost M R. 2023. Quaternary ammonium-functionalized UiO-66-Sal as an efficient and fast adsorbent for nitrate removal from water. Applied Surface Science, 615, 156391.

Mohan B, Kamboj A, Virender, Singh K, Priyanka, Singh G, Pombeiro A J L, Ren P. 2023. Metal-organic frameworks (MOFs) materials for pesticides, heavy metals, and drugs removal: Environmental safety. Separation and Purification Technology, 310, 123175.

Moradi E, Rahimi R, Safarifard V. 2019. Sonochemically synthesized microporous metal-organic framework representing unique selectivity for detection of Fe3+ ions. Polyhedron, 159, 251–258.

Morales-Cámara S, Parra-Torrejón B, Rodríguez-Diéguez A, Delgado-López J M, Ramírez-Rodríguez G B, Rojas S. 2024. ZIF-8@Hydroxyapatite composite as a high potential material for prolonged delivery of agrochemicals. ACS Applied Materials & Interfaces, 16, 29305–29313.

Nguyen T T, Nguyen M K, Kumar V, Do H H, Le A T K, Nguyen A V, Gwag J S, Nam P C, Trung L G. 2024. Optimal adsorption of pefloxacin antibiotics from aqueous solutions: improved performance with metal-organic framework MIL-101(Cr). Colloids and Surfaces (A: Physicochemical and Engineering Aspects), 689, 133642.

Ni Z, Masel R I. 2006. Rapid production of metal-organic frameworks via microwave-assisted solvothermal synthesis. Journal of the American Chemical Society, 128, 12394–12395.

O’Keeffe M, Peskov M A, Ramsden S J, Yaghi O M. 2008. The reticular chemistry structure resource (RCSR) database of, and symbols for, crystal nets. Accounts of Chemical Research, 41, 1782–1789.

Pan S Y, Hsiao Y Y, Negi S, Matsagar B M, Wu K C W. 2024. Green synthesis of waste-derived metal-organic frameworks for organic substance extraction from piggery wastewater as biofertilizers. ACS Sustainable Chemistry & Engineering, 12, 17793–17805.

Pang J D, Zhang Z Q, Zhang S T, Guo X Y, Chen Q, Zhang X W, Zhou H L, Gong W, Shah S S A, Zhong C L, Li J R, Zhang J P, Cui Y, Jiang H L, Bu X H. 2025. Recent progress in metal-organic frameworks: part I-material preparation. Science China (Chemistry), 68, 1230–1286.

Pattappan D, Mohankumar A, Kumar R T R, Palanisamy S, Lai Y T, Huh Y S, Shim J J, Haldorai Y. 2023. Visible light photocatalytic activity of a FeCo metal-organic framework for degradation of acetaminophen and 2,4-dichlorophenoxyacetic acid and a nematode-based ecological assessment. Chemical Engineering Journal, 464, 142676.

Pedrero D, Edo C, Fernández-Piñas F, Rosal R, Aguado S. 2024. Efficient removal of nanoplastics from water using mesoporous metal organic frameworks. Separation and Purification Technology, 333, 125816.

Prada J A P, Navarro T A H, Chua S L, Granados A M, Pao C W, Fracaroli A M, Bedford N M. 2025. Degradation of glyphosate to benign N-formyl glycine using MOF-808 nanocrystals. Angewandte Chemie (International Edition), 64, e202424540.

Pu H, Xie Y, Wei Q, Sun D-W. 2023. Anchoring Au on UiO-66 surface with thioglycolic acid for simultaneous SERS detection of paraquat and diquat residues in cabbage. Microchemical Journal, 190, 108563.

Ramesha B M, Meynen V. 2020. Advances and challenges in the creation of porous metal phosphonates. Materials, 13, 5366.

Ren L, Zhao J, Li W, Li Q, Zhang D, Fang W, Yan D, Li Y, Wang Q, Jin X, Cao A. 2022. Site-specific controlled-release imidazolate framework-8 for dazomet smart delivery to improve the effective utilization rate and reduce biotoxicity. Journal of Agricultural and Food Chemistry, 70, 5993–6005.

Rojas-Guerrero C A, Villanueva-Rodríguez M, Guzmán-Mar J L, Hernández-Ramírez A, Cedillo-González E I, Rodríguez F E L, Hinojosa-Reyes L. 2023. Solar photocatalytic degradation of polyethylene terephthalate nanoplastics: evaluation of the applicability of the TiO2/MIL-100(Fe) composite material. Journal of Environmental Chemical Engineering, 11, 110415.

Rojas S, Rodríguez-Diéguez A, Horcajada P. 2022. Metal-organic frameworks in agriculture. ACS Applied Materials & Interfaces, 14, 16983–17007.

Saleh I A, Zouari N, Al-Ghouti M A. 2020. Removal of pesticides from water and wastewater: chemical, physical and biological treatment approaches. Environmental Technology & Innovation, 19, 101026.

Salehi M M, Hassanzadeh-Afruzi F, Esmailzadeh F, Choopani L, Rajabi K, Kuzekanan H N, Azizi M, Yeganeh F E, Demchuk O M, Maleki A. 2024. Chlorpyrifos and diazinon elimination through pAAm-g-XG/HKUST-1@Fe3O4 biopolymer nanoadsorbent hydrogel from wastewater: Preparation, characterization, kinetics and isotherm. Separation and Purification Technology, 334, 126097.

Salehipour M, Nikpour S, Rezaei S, Mohammadi S, Rezaei M, Ilbeygi D, Hosseini-Chegeni A, Mogharabi-Manzari M. 2023. Safety of metal-organic framework nanoparticles for biomedical applications: an
in vitro toxicity assessment. Inorganic Chemistry Communications, 152, 110655.

Samal M, Panda J, Biswal B P, Sahu R. 2018. Kitchen grinder: a tool for the synthesis of metal-organic frameworks towards size selective dye adsorption. Crystengcomm, 20, 2486–2490.

Schlesinger M, Schulze S, Hietschold M, Mehring M. 2010. Evaluation of synthetic methods for microporous metal-organic frameworks exemplified by the competitive formation of [Cu2(btc)3(H2O)3] and [Cu2(btc)(OH)(H2O)]. Microporous and Mesoporous Materials, 132, 121–127.

Shahabinejad H, Binazadeh M, Esmaeilzadeh F, Hashemi F, Mousavi S M. 2024. Optimization of cerium-based metal-organic framework synthesis for maximal sonophotocatalytic tetracycline degradation. Scientific Reports, 14, 16887.

Shao Q S, Ding Y T, Liu W X, Guan J, Meng G, Kuang T R, Wang D S. 2025. Bandgap engineering on UiO-66 metal-organic framework derivatives for solar-driven seawater desalination. Advanced Science, 12, 2502989.

Shu L, Zhang X F, Yang S T, Qiu J H, Yao J F. 2024. Integration of CuS@MIL-100 into cellulose hydrogel for synergistic seawater desalination and photocatalytic decontamination. Separation and Purification Technology, 334, 125971.

Sifaoui I, Pacheco-Fernández I, Piñero J E, Pino V, Lorenzo-Morales J. 2021. A simple in vivo assay using amphipods for the evaluation of potential biocompatible metal-organic frameworks. Frontiers in Bioengineering and Biotechnology, 9, 584115.

Sikdar A, Majumdar A, Gogoi A, Dutta P, Borah M, Maiti S, Gogoi C, Reddy K A, Oh Y, Maiti U N. 2021. Diffusion driven nanostructuring of metal-organic frameworks (MOFs) for graphene hydrogel based tunable heterostructures: highly active electrocatalysts for efficient water oxidation. Journal of Materials Chemistry, 9, 7640–7649.

Solovyeva M, Krivosheeva I, Gordeeva L, Aristov Y. 2021. MIL-160 as an adsorbent for atmospheric water harvesting. Energies, 14, 3586.

Son W J, Kim J, Kim J, Ahn W S. 2008. Sonochemical synthesis of MOF-5. Chemical Communications, 47, 6336–6338.

Souza B E, Möslein A F, Titov K, Taylor J D, Rudic S, Tan J C. 2020. Green reconstruction of MIL-100 (Fe) in water for high crystallinity and enhanced guest encapsulation. ACS Sustainable Chemistry & Engineering, 8, 8247–8255.

Su C, Wu Z X, Zhang J, Li K Y, Kong Y Q, Zhang N Q, Yang Y P. 2024. A high-performance solar-driven atmospheric water harvester for arid regions based on a self-assembled MOF-on-MOF heterostructure. Applied Materials Today, 38, 102247.

Sun B T, Bilal M, Jia S R, Jiang Y H, Cui J D. 2019. Design and bio-applications of biological metal-organic frameworks. Korean Journal of Chemical Engineering, 36, 1949–1964.

Sun L, Hou C Q, Wei N, Tan Y F, Liang Q W, Feng J G. 2023. pH/cellulase dual environmentally responsive nano-metal organic frameworks for targeted delivery of pesticides and improved biosafety. Chemical Engineering Journal, 478, 147294.

Taddei M, Costantino F, Ienco A, Comotti A, Dau P V, Cohen S M. 2013. Synthesis, breathing, and gas sorption study of the first isoreticular mixed-linker phosphonate based metal-organic frameworks. Chemical Communications, 49, 1315–1317.

Tan J, Ren H, Zhao Z, Xin X, Shi Y, Yang D, Jiang Z. 2023. Ca2+ doped metal organic frameworks for enhanced photocatalytic ammonia synthesis. Chemical Engineering Journal, 466, 143259.

Tan K L, Foo K Y. 2021. Preparation of MIL-100 via a novel water-based heatless synthesis technique for the effective remediation of phenoxyacetic acid-based pesticide. Journal of Environmental Chemical Engineering, 9, 104923.

Tanihara A, Kikuchi K, Konno H. 2021. Insight into the mechanism of heavy metal removal from water by monodisperse ZIF-8 fine particles. Inorganic Chemistry Communications, 131, 108782.

Tari N E, Tadjarodi A, Tamnanloo J, Fatemi S. 2016. One pot microwave synthesis of MCM-41/Cu based MOF composite with improved CO2 adsorption and selectivity. Microporous and Mesoporous Materials, 231, 154–162.

Troyano J, Çamur C, Garzón-Tovar L, Carné-Sánchez A, Imaz I, Maspoch D. 2020. Spray-drying synthesis of MOFs, COFs, and related composites. Accounts of Chemical Research, 53, 1206–1217.

Wahan S K, Chawla P A, Kaur R, Bhargava G. 2025. Recent developments in the mechanochemical mediated innovative approaches for cycloaddition reactions. Synthetic Communications, 55, 351–372.

Wang C Y, Qin J C, Yang Y W. 2023. Multifunctional metal-organic framework (MOF)-based nanoplatforms for crop protection and growth promotion. Journal of Agricultural and Food Chemistry, 71, 5953–5972.

Wang C C, Li J R, Lv X L, Zhang Y Q, Guo G S. 2014. Photocatalytic organic pollutants degradation in metal-organic frameworks. Energy & Environmental Science, 7, 2831–2867.

Wang D Y, Yao H C, Ye J S, Gao Y, Cong H L, Yu B. 2024. Metal-organic frameworks (MOFs): classification, synthesis, modification, and biomedical applications. Small, 20, 2404350.

Wang J J, Pu C Y, Lu L, Muddassir M, Srivastava S, Jayswal M R, Wang X X, Kumar A. 2024. 5-(4′-carboxylphenoxy) isophthalic acid and 1, 4-bis(1-imidazolyl)benzene appended Co(II)-based MOF as efficient photocatalyst for nitrofurantoin degradation. Applied Organometallic Chemistry, 38, e7609.

Wang J L, Wang W K, Li J G, Mu X Y, Yan X Y, Wang Z R, Su J B, Lei T, Wang C B. 2021. Universal strategy to prepare a flexible photothermal absorber based on hierarchical Fe-MOF-74 toward highly efficient solar interfacial seawater desalination. ACS Applied Materials & Interfaces, 13, 45944–45956.

Wang K, Huang H, Zhou X, Wang Q, Li G, Shen H, She Y, Zhong C. 2019. Highly chemically stable MOFs with trifluoromethyl groups: effect of position of trifluoromethyl groups on chemical stability. Inorganic Chemistry, 58, 5725–5732.

Wang W, Ghafar M A, Liuyang L, Haq I U, Cui L, Yuan H, Wang L. 2025. Nanoscale metal-organic frameworks for the co-delivery of cycloxaprid and pooled sirnas to enhance control efficacy in Diaphorina citri. Journal of Agricultural and Food Chemistry, 73, 3353–3362.

Wang Y, Shaghaleh H, Hamoud Y A, Zhang S, Li P, Xu X, Liu H. 2021. Synthesis of a pH-responsive nano-cellulose/sodium alginate/MOFs hydrogel and its application in the regulation of water and N-fertilizer. International Journal of Biological Macromolecules, 187, 262–271.

Wei F H, Ren Q H, Yu X, Wang Y, Chen H L, Liang Z. 2024. Preparation of Zn/Zr-MOFs by microwave-assisted ball milling and adsorption of lomefloxacin hydrochloride and levofloxacin hydrochloride in wastewater. Environmental Research, 252, 118941.

Wei F H, Xiao L, Ren Q H, Wang K, Qin L, Chen H L, Ma Y F, Liang Z. 2022. The application of bimetallic metal-organic frameworks for antibiotics adsorption. Journal of Saudi Chemical Society, 26, 101562.

Wei H, Geng Z, Wang H, Zhao Y, Yang L, Zhou Z. 2025. Dual emission of Eu-based composites for sensitive detection of tetracycline by mixed ligand regulation. Inorganic Chemistry Communications, 172, 113754.

Wei J Z, Gong F X, Sun X J, Li Y, Zhang T, Zhao X J, Zhang F M. 2019. Rapid and low-cost electrochemical synthesis of UiO-66-NH2 with enhanced fluorescence detection performance. Inorganic Chemistry, 58, 6742–6747.

Wu K, Du C W, Ma F, Shen Y Z, Zhou J M. 2019. Optimization of metal-organic (citric acid) frameworks for controlled release of nutrients. Rsc Advances, 9, 32270–32277.

Wu K, Li W J, Ma F, Gan F Q, Zhou J M, Zeng H B, Du C W. 2024. Urea-loaded core-shell MOF/silica nanocarriers for continuous nitrogen release to crops. ACS Applied Nano Materials, 7, 11645–11654.

Wu K, Xu X B, Ma F, Du C W. 2022. Fe-based metal-organic frameworks for the controlled release of fertilizer nutrients. ACS Omega, 7, 35970–35980.

Wu K, Zhang X, Du C, Zhang R, Zhou R, Wang S, Guan Y, Jiang L, Li Y, Gan F. 2025. Enhanced phosphate removal from water via hierarchically porous metal-organic frameworks. Journal of Environmental Chemical Engineering, 13, 115311.

Xing G Q, Wang C, Liu K, Luo B, Hou P C, Wang X D, Dong H T, Wang J S, Li A X. 2022. A probe-free electrochemical immunosensor for methyl jasmonate based on a Cu-MOF-carboxylated graphene oxide platform. RSC Advances, 12, 16688–16695.

Xu K Q, Shahab A, Li J Y, Wang D Q, Li Y H, Idris A M, Xiao H. 2025. A highly efficient and recyclable zirconium-based metal organic framework for the effective removal of nanoplastics from multiple aqueous environments. Process Safety and Environmental Protection, 194, 1101–1115.

Yaghi O M, Li G M, Li H L. 1995. Selective binding and removal of guests in a microporous metal-organic framework. Nature, 378, 703–706.

Yan Y, Ni M, Wang F, Yu Y, Gong X, Huang Y, Tao W, Li C, Wang F. 2022. Metal-organic framework-based biosensor for detecting hydrogen peroxide in plants through color-to-thermal signal conversion. ACS Nano, 16, 15175–15187.

Yang C, Zhu Y, Chen J, Wu T, Wang J, Zhao X, Sun W, Lin H, Lv S. 2022. Graphene/Fe@N-doped carbon hybrid derived from spent MOF adsorbent as efficient persulfate activator for degradation of tetracycline hydrochloride. Chemical Engineering Journal, 431, 133443.

Yang M C, Tang C Y, Han M Q, Tong Z H, Yang Y C, Gao L W, Su B N, Chen D L, Li J Y, Zhang L, Zhang S G. 2025. Tailoring MOF-303 reinforced biopolymer hybrid coatings with hierarchically porous architectures for precision nitrogen delivery in sustainable agriculture. Advanced Sustainable Systems, 9, 2500185.

Yao Q, Gómez A B, Su J, Pascanu V, Yun Y F, Zheng H Q, Chen H, Liu L F, Abdelhamid H N, Martín-Matute B, Zou X D. 2015. Series of highly stable isoreticular lanthanide metal-organic frameworks with expanding pore size and tunable luminescent properties. Chemistry of Materials, 27, 5332–5339.

Yilmaz G, Meng F L, Lu W, Abed J, Peh C K N, Gao M, Sargent E H, Ho G W. 2020. Autonomous atmospheric water seeping MOF matrix. Science Advances, 6, eabc8605.

Yu J, Cheng Y, Zhang X, Zhou L, Song Z, Nezamzadeh-Ejhieh A, Huang Y. 2025. Application progress of nano-platforms based on metal-organic frameworks (MOFs) in modern agriculture. Journal of Environmental Chemical Engineering, 13, 116870.

Yuan S, Feng L, Wang K C, Pang J D, Bosch M, Lollar C, Sun Y J, Qin J S, Yang X Y, Zhang P, Wang Q, Zou L F, Zhang Y M, Zhang L L, Fang Y, Li J L, Zhou H C. 2018. Stable metal-organic frameworks: design, synthesis, and applications. Advanced Materials, 30, 1704303.

Zain M, Ma H, Ur Rahman S, Nuruzzaman M, Chaudhary S, Azeem I, Mehmood F, Duan A, Sun C. 2024. Nanotechnology in precision agriculture: advancing towards sustainable crop production. Plant Physiology and Biochemistry, 206, 108244.

Zeng M F, Li J, Fan S T, Song M M, Wang J X, Guo D L, Zhang Y T, Li B J, Zhang S. 2025. Internally extended growth of hierarchical MOF-on-MOF nanostructures for adsorption. ACS Applied Nano Materials, 8, 11437–11446.

Zhang C Q, Zhang Y, Deng R, Yuan L, Zou Y Y, Bao T, Zhang X C, Wei G F, Yu C Z, Liu C. 2024. Enabling logistics automation in nanofactory: cobalt phosphide embedded metal-organic frameworks for efficient electrocatalytic nitrate reduction to ammonia. Advanced Materials, 36, 2313844.

Zhang J, White G B, Ryan M D, Hunt A J, Katz M J. 2016. Dihydrolevoglucosenone (Cyrene) as a green alternative to N,N-Dimethylformamide (DMF) in MOF synthesis. ACS Sustainable Chemistry & Engineering, 4, 7186–7192.

Zhang M, Zhang J, Che X, Jiang J, Tu Q, Wang J. 2024. Biomimetic mineralization-based in situ growth of AuNCs@ZIF-8 on paper fibers for visual detection of copper ions. Talanta, 268, 125364.

Zhang P, Kang X, Tao L, Zheng L, Xiang J, Duan R, Li J, Chen P, Xing X, Mo G J C C. 2023. A new route for the rapid synthesis of metal-organic frameworks at room temperature. CCS Chemistry, 5, 1462–1469.

Zhang Q, Tang C, Han M, Tong Z, Cao L, Dong S, Yang Y, Li J, Cao X, Zhang J, Wang K, Zhang S. 2025. MOF-modified biobased polyol derived from a castor-coated fertilizer for precise controlled release of nutrients. ACS Applied Polymer Materials, 7, 7113–7121.

Zhang R, Lv G, Du C, Ma F, Liu S, Gan F, Wu K. 2025. Hierarchically porous metal-organic frameworks-based controlled-release fertilizer: improved nutrient loading and rice growth. Agronomy, 15, 2334.

Zhang R, Wang B, Wang F, Chen S M, Zhang J. 2022. Syntheses of ferrocene-functionalized indium-based metal-organic frameworks for third order nonlinear optical application. Inorganic Chemistry Frontiers, 10, 201–210.

Zhang W, Liu Y C, Jeppesen H S, Pinna N. 2024. Stöber method to amorphous metal-organic frameworks and coordination polymers. Nature Communications, 15, 5463.

Zhang X, Li M, Zhao Y-l, Li X-Y, Fang Y, Xie L H, Li J R. 2025. Simultaneous capture of N2O and CO2 from a N2O/N2/CO2/O2 mixture with a Ni(II)-pyrazolecarboxylate framework. Journal of the American Chemical Society, 147, 17042–17048.

Zhang Y, Meng X-Q, Ding H-J, Wang X, Yu M-H, Zhang S-M, Chang Z, Bu X-H. 2019. Rational construction of breathing metal-organic frameworks through synergy of a stretchy ligand and highly variable π–π interaction. ACS Applied Materials & Interfaces, 11, 20995–21003.

Zhang Z, Bai L, Liu T, Zhang H, Li Z, Liu Q, Han J. 2024. Aluminium-based metal-organic frameworks for the colorimetric ethephon detection in fruit by paper microsensor. Journal of Science (Advanced Materials and Devices), 9, 100769.

Zhao H J, Dong J L, Chen S J, Wang H, Zhao G D. 2024. Metal-organic frameworks and their composites for carbon dioxide capture: recent advances and challenges. Fuel, 378, 132973.

Zhao X, Zhang L, Liu B, Zhang C, Zhao H, Wang C-C, Liu D. 2023. Recycling of stainless steel pickling wastewater and polyethylene terephthalate plastic: a total-waste synthesis of metal-organic framework. Progress in Natural Science (Materials International), 33, 478–485.

Zhao Y Q, Qin K, Zhou Y Q, Liu W, Gao Z X, Peng Y. 2025. Hierarchically porous Cu-MOF fiber membrane enables instantaneous and continuous removal of organophosphorus pesticides in water. Journal of Environmental Chemical Engineering, 13, 115877.

Zheng Z C, Sun Z J, Li M, Yang J S, Yang Y K, Liang H, Xiang H M, Meng J, Zhou X, Liu L W, Wu Z B, Yang S. 2024. An update review on biopolymer xanthan gum: properties, modifications, nanoagrochemicals, and its versatile applications in sustainable agriculture. International Journal of Biological Macromolecules 281, 136562.

Zhou D D, Lu Z H, Chen M, Zhuang L Y, Cao Y W, Liu X, Senosy I A, Yang Z H. 2022. A novel magnetic double MOF composite is synthesized for removing azole fungicides economically and efficiently. Applied Surface Science, 594, 153441.

Zhou H, Hui X D, Li D X, Hu D L, Chen X, He X M, Gao L X, Huang H, Lee C, Mu X J. 2020. Metal-organic framework-surface-enhanced infrared absorption platform enables simultaneous on-chip sensing of greenhouse gases. Advanced Science, 7, 2001173.

Zhou J, Liu G, Zhang Y, Lin Z, Wang M, Jiao B, Zhao Y, Chen G, Yang X, Lv J, Xu D. 2025. Tannic acid-Fe3+ network-coated defective bimetallic ZnM-ZIF (M=Cu and Ni) for enhanced pesticide-loading capacity and pest control. ACS Sustainable Chemistry & Engineering, 13, 5131–5144.

Zhou X, Liu X, Yu X, Liu Q, Bai T, Gao M, Xu C, Zhang X, Zhu M, Cheng Y. 2024. Hybrid water-harvesting channels delivering wide-range and supersensitive passive fluorescence humidity sensors. ACS Applied Materials & Interfaces, 16, 27794–27803.

Zhou Y, Xiong J X, Wang L, Li F, Bai H P, Wang S X, Yang X J. 2024. Multi-ligand strategy for enhanced removal of heavy metal ions by thiol-functionalized defective Zr-MOFs. Journal of Hazardous Materials, 479, 135723.

Zhu B J, Zou R Q, Xu Q. 2018. Metal-organic framework based catalysts for hydrogen evolution. Advanced Energy Materials, 8, 1801193.