Dissipation and Adsorption Behavior of the Insecticide Ethiprole on Various Cultivated Soils in China

doi:10.1016/S2095-3119(13)60685-1

Journal of Integrative Agriculture ›› 2014, Vol. 13 ›› Issue (11): 2471-2478.DOI: 10.1016/S2095-3119(13)60685-1

Dissipation and Adsorption Behavior of the Insecticide Ethiprole on Various Cultivated Soils in China

LIU Xin-gang, DONG Feng-shou, XU Jun, YUAN Shan-kui , ZHENG Yong-quan

1、Key Laboratory of Integrated Pest Management in Crops, Ministry of Agriculture/Institute of Plant Protection, Chinese Academy of
Agricultural Sciences, Beijing 100193, P.R.China
2、Institute for the Control of Agrochemicals, Ministry of Agriculture, Beijing 100125, P.R.China

收稿日期:2013-07-04 出版日期:2014-11-06 发布日期:2014-11-14
通讯作者: ZHENG Yong-quan, Tel: +86-10-62815908, E-mail: zhengyongquan@ippcaas.cn
作者简介:LIU Xin-gang, Tel: +86-10-62815938, E-mail: xgliu@ippcaas.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (31272070).

Dissipation and Adsorption Behavior of the Insecticide Ethiprole on Various Cultivated Soils in China

LIU Xin-gang, DONG Feng-shou, XU Jun, YUAN Shan-kui , ZHENG Yong-quan

1、Key Laboratory of Integrated Pest Management in Crops, Ministry of Agriculture/Institute of Plant Protection, Chinese Academy of
Agricultural Sciences, Beijing 100193, P.R.China
2、Institute for the Control of Agrochemicals, Ministry of Agriculture, Beijing 100125, P.R.China

Received:2013-07-04 Online:2014-11-06 Published:2014-11-14
Contact: ZHENG Yong-quan, Tel: +86-10-62815908, E-mail: zhengyongquan@ippcaas.cn
About author:LIU Xin-gang, Tel: +86-10-62815938, E-mail: xgliu@ippcaas.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (31272070).

摘要/Abstract

摘要： In this study, the hydrolysis of the insecticide ethiprole in buffered solutions at pH 4.0, 7.0 and 9.0, respectively, and the degradation and adsorption-desorption behaviors of ethiprole in five agricultural soil samples from China were investigated. The half-lives under anaerobic conditions were faster than that in the aerobic experiment. Ethiprole was relatively stable under both acidic and neutral conditions while it was readily hydrolyzed under alkaling condition. The sorption of ethiprole on five soils was well described by the linear and Freundlich equation and mainly governed by soil organic matter. The exothermic process of ethiprole adsorption can also be well explained by physical adsorption. A weak adsorption capacity was observed in all soils, which could readily lead to leaching problems.

关键词: ethiprole , adsorption , desorption , hydrolysis , soil dissipatio

Abstract: In this study, the hydrolysis of the insecticide ethiprole in buffered solutions at pH 4.0, 7.0 and 9.0, respectively, and the degradation and adsorption-desorption behaviors of ethiprole in five agricultural soil samples from China were investigated. The half-lives under anaerobic conditions were faster than that in the aerobic experiment. Ethiprole was relatively stable under both acidic and neutral conditions while it was readily hydrolyzed under alkaling condition. The sorption of ethiprole on five soils was well described by the linear and Freundlich equation and mainly governed by soil organic matter. The exothermic process of ethiprole adsorption can also be well explained by physical adsorption. A weak adsorption capacity was observed in all soils, which could readily lead to leaching problems.

Key words: ethiprole , adsorption , desorption , hydrolysis , soil dissipatio

LIU Xin-gang, DONG Feng-shou, XU Jun, YUAN Shan-kui , ZHENG Yong-quan. Dissipation and Adsorption Behavior of the Insecticide Ethiprole on Various Cultivated Soils in China[J]. Journal of Integrative Agriculture, 2014, 13(11): 2471-2478.

参考文献

Agbenin J O, Olojo L A. 2004. Competitive adsorption ofcopper and zinc by a Bt horizon of a savanna Alfisol asaffected by pH and selective removal of hydrous oxidesand organic matter. Geoderma, 119, 85-95

Barriuso E, Calvet R. 1992. Soil type and herbicidesadsorption. International Journal of EnvironmentalAnalytical Chemistry, 46, 117-128

Bermudez-Couso A, Fernandez-Calvino D, Pateiro-Moure M,Garrido-Rodriguez B, Novoa-Munoz J C, Estevez M A.2011. Adsorption and desorption behavior of metalaxyl inintensively cultivated acid soils. Journal of Agriculturaland Food Chemistry, 59, 7286-7293

Caboni P, Sammelson R E, Casida J E. 2003. Phenylpyrazoleinsecticide photochemistry, metabolism, and GABAergicaction: Ethiprole compared with fipronil. Journal ofAgricultural and Food Chemistry, 51, 7055-7061

Flores C, Morgante V, González M, Navia R, Seeger M. 2009.Adsorption studies of the herbicide simazine in agriculturalsoils of the Aconcagua valley, central Chile. Chemosphere,74, 1544-1549.

FSC (Food Safety Commission). 2004. Ethiprole. [2011-10-10]. http://www.fsc.go.jp/english/ethiprole_fullreport.pdfFernandes M C, Cox L, Hermosin M C, Cornejo J. 2006.Organic amendments affecting sorption, leaching anddissipation of fungicides in soils. Pest ManagementScience, 62, 1207-1215

.GB/T17296-2009. 2009. Classification and code for Chinesesoil. National Standard of the People’s Republic of China.pp. 6-81. (in Chinese)

He Y, Xu J, Wang H, Ma Z, Chen J. 2006. Detailed sorptionisotherms of pentachlorophenol on soils and its correlationwith soil properties. Environmental Research, 101, 362-372

Kmellar B, Fodor P, Pareja L, Ferrer C, Martínez-UrozM, Valverde A, Fernandez-Alba A. 2008. Validation　and uncertainty study of a comprehensive list of 160pesticide residues in multi-class vegetables by liquidchromatography-tandem mass spectrometry. Journal ofChromatography (A), 1215, 37-50

Kumar M, Philip L. 2006. Adsorption and desorptioncharacteristics of hydrophobic pesticide endosulfan in fourIndian soils. Chemosphere, 62, 1064-1077.

Lacroix M, Puel S, Toutain P, Viguie C. 2010. Quantificationof fipronil and its metabolite fipronil sulfone in rat plasmaover a wide range of concentrations by LC/UV/MS.Journal of Chromatography (B), 878, 1934-1938

PPDB (pesticide properties database). 2009. Ethiprole. [2014-8-2] http://sitem.herts.ac.uk/aeru/iupac/Reports/1227.htm

Tahar A, Choubert J M, Coquery M. 2013. Xenobioticsremoval by adsorption in the context of tertiary treatment:A mini review. Envionmental Science and PollutionReasearch, 20, 5085-5095

Tang Z, Zhang W, Chen Y. 2009. Adsorption and desorptioncharacteristics of monosulfuron in Chinese soils. Journalof Hazardous Materials, 166, 1351-1356

USEPA (US Environmental Protection Agency). 2004.Pesticide fact sheet: Ethiprole. [2010-07-21] http://www.alanwood.net/pesticides/ethiprole.html

Di Vincenzo J P, Sparks D L. 1997. Slow sorption kineticsof pentachlorophenol on soil: Concentration effects.Environmental Science and Technology, 31, 977-983

Yang H, Xue B, Li L, Zhou S, Tu Y, Lin C. 2008. Hydrolysisand soil sorption of insecticide pyraclofos. Journal ofEnvironmental Science and Health (Part B: Pesticides,Food Contaminants, and Agricultural Wastes), 43, 219-223

Ying G G, Kookana R S. 2001. Sorption of fipronil and itsmetabolites on soils from South Australia. Journal ofEnvironmental Science and Health (Part B: PesticidesFood Contaminants and Agricultural Wastes), 36, 545-558

Ying G G, Yu X Y, Kookana R S. 2007. Biological degradationof triclocarban and triclosan in a soil under aerobic andanaerobic conditions and comparison with environmentalfate modelling. Environmental Pollution, 150, 300-305

You S J, Yin Y, Allen H E. 1999. Partitioning of organic matterin soils: Effects of pH and water/soil ratio. Science of theTotal Environment, 227, 155-160

Yu X Y, Ying G G, Kookana R S. 2006. Sorption anddesorption behaviors of diuron in soils amended withcharcoal. Journal of Agricultural and Food Chemistry,54, 8545-8550

Zhang H, Qian M R, Wang X Q, Liu F, Wang X Y, Xu H, Qi P P,Wang M H. 2012. determination of ethiprole enantiomersresidue in rices using solid phase extraction-liquidchromatography tandem mass spectrometry. ChineseJournal of Analystical Chemistry, 40, 883-887 (in Chinese)

Zhang J, He M. 2010. Effect of structural variations on sorptionand desorption of phenanthrene by sediment organicmatter. Journal of Hazardous Materials, 184, 432-438

Zhao X P, Wu C X, Wang Y H, Cang T, Chen L P, Yu R X,Wang Q. 2012. Assessment of toxicity risk of insecticidesused in rice ecosystem on Trichogramma japonicum, anegg parasitoid of rice Lepidopterans. Journal of EconomicEntomology, 105, 92-101

[1]	LIU Jing-jing, LIU Xiao-ping, REN Ji-wei, ZHAO Hong-yan, YUAN Xu-feng, WANG Xiao-fen, Abdelfattah Z M Salem, CUI Zong-jun. The effects of fermentation and adsorption using lactic acid bacteria culture broth on the feed quality of rice straw[J]. Journal of Integrative Agriculture, 2015, 14(3): 503-513.
[2]	LI Cui-lan, JI Fan, WANG Shuai, ZHANG Jin-jing, GAO Qiang, WU Jing-gui, ZHAO Lan-po, WANG Li-chun, ZHENG Li-rong. Adsorption of Cu(II) on humic acids derived from different organic materials[J]. Journal of Integrative Agriculture, 2015, 14(1): 168-177.
[3]	JIANG Tian-yu, XU Ren-kou, GU Tian-xia , JIANG Jun. Effect of Crop-Straw Derived Biochars on Pb(II) Adsorption in Two Variable Charge Soils[J]. Journal of Integrative Agriculture, 2014, 13(3): 507-516.
[4]	WU Chun-xian, NIE Guo, ZHANG Zhong-ming, WANG Guang-cheng, GAO Li-ming , WANG Jinjun. Influence of Organic Amendments on Adsorption, Desorption and Leaching of Methiopyrisulfuron in Soils[J]. Journal of Integrative Agriculture, 2013, 12(9): 1589-1597.
[5]	LIAO Yu-lin, ZHENG Sheng-xian, NIE Jun, XIE Jian, LU Yan-hong , QIN Xiao-bo. Long-Term Effect of Fertilizer and Rice Straw on Mineral Composition and Potassium Adsorption in a Reddish Paddy Soil[J]. Journal of Integrative Agriculture, 2013, 12(4): 694-710.
[6]	CAO Jia, DIAO Xiao-ping , HU Ji-ye. Hydrolysis and Photolysis of Herbicide Clomazone in Aqueous Solutions and Natural Water Under Abiotic Conditions[J]. Journal of Integrative Agriculture, 2013, 12(11): 2074-2082.
[7]	CHEN Jian-sheng, TIAN Ji-chun, DENG Zhi-ying, ZHANG Ying-xiang, FENG Shou-li, YAN Zuo-chen, ZHANG Xin-ye, YUAN Hui-qing. Effects of Papain Hydrolysis on the Pasting Properties of Wheat Flour[J]. Journal of Integrative Agriculture, 2012, 12(12): 1948-1957.

Dissipation and Adsorption Behavior of the Insecticide Ethiprole on Various Cultivated Soils in China

Dissipation and Adsorption Behavior of the Insecticide Ethiprole on Various Cultivated Soils in China

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 7

编辑推荐

Metrics